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Tokyo Institute of Technology

OTSUKA LABORATORY

プロフィールPROFILE

プロフィール


青木 大輔　（あおき　だいすけ）


略歴

2006 山形大学工学部機能高分子工学科 卒業
2008 山形大学院理工学研究科生体センシング機能工学科修士課程修了
2008-2011 民間企業
2012-2013 Visiting scientist at Waterloo university, Canada
2014 東京工業大学理工学研究科有機・高分子物質専攻博士課程修了　博士（工学）　
2014-2017 東京工業大学理工学研究科有機・高分子物質専攻 特任助教 (ACT-C プロジェクト)
2017-東京工業大学物質理工学院応用化学系　助教
2018-科学技術振興機構さきがけ研究者（兼任）

所属学会

日本化学会
高分子学会
有機合成化学協会
アメリカ化学会

受賞等

2005 高分子学会東北支部研究発表会 若手優秀発表賞
2011 第1回CSJ化学フェスタ 優秀ポスター発表賞
2012 日経テクノルネサンス・ジャパン 優良賞
2012 第92回日本化学会春季年会 学生講演賞　
2013 第3回CSJ化学フェスタ 優秀ポスター発表賞
2013 The 13th Pacific Polymer Conference Best Poster Award　
2013 The workshop on Education and Research Center for Materials Innovation Poster Award
2014 第14回リングチューブ超分子研究会シンポジウム　優秀ポスター賞
2014 関東高分子若手研究会　論文発表賞
2014 第94回日本化学会春季年会 学生講演賞
2017 第97回日本化学会春季年会 優秀講演賞 (学術)
2018 東工大物資理工学院研究奨励賞
2018 平成29年度東京工業大学 手島精一記念研究賞（研究論文賞）
2018 高分子研究奨励賞（高分子学会）
2019 東京工業大学工系教育賞
2019 第99回日本化学会春季年会 優秀講演賞(学術)
2019 東工大物質理工学院研究奨励賞
2020 ゴム協会第67回優秀論文賞
2020 ヤングサイエンティスト講演賞
2021 Soft Matter Emerging Investigators
2021 精密ネットワーク研究会 第14回若手シンポジウム優秀発表賞
2021 日本化学会第101回春季年会 若い世代の特別講演賞

座右の銘

為せば成る

趣味

ベンチプレス

Publication List

  1. T. Abe, R. Takashima, T. Kamiya, C. P. Foong, K. Numata, D. Aoki, H. Otsuka, Plastics to Fertilizers: Chemical Recycling of a Bio-based Polycarbonate as a Fertilizer Source, Green. Chem., 2021, in press. DOI: 10.1039/D1GC02327F

  2. D. Aoki, G. Aibara, T. Takata, Reversible Cyclic-Linear Topological Transformation using a Long-Range Rotaxane Switch, Polym. Chem., 2021, in press. DOI:10.1039/D1PY01197A

  3. H. Sato, D. Aoki, H. Marubayashi, S. Uchida, H. Sogawa, S. Nojima, X. Liang, K. Nakajima, T. Hayakawa, T. Takata, Topology-transformable block copolymers based on a rotaxane structure: change in bulk properties with same composition, Nat. Commun., 2021, 12, 6175.

  4. Y. Lu, H. Sugita, K. Mikami, D. Aoki, H. Otsuka, Mechanochemical Reactions of Bis(9-methylphenyl-9-fluorenyl) Peroxides and Their Applications in Cross-Linked Polymers, J. Am. Chem. Soc., 2021, 143, 17744.

  5. H. Yokochi, M. Ohira, M. Oka, S. Honda, L. Xiang, D. Aoki, H. Otsuka, Topology Transformation Toward Cyclic, Figure-eight-shaped, and Cross-linked Polymers Based on the Dynamic Behavior of a Bis(hindered amino)disulfide Linker, Macromolecules, 2021, 54, in press. DOI: 10.1021/acs.macromol.1c01437.

  6. R. Takashima, D. Aoki, H. Otsuka, Synthetic Strategy for Mechanically Interlocked Cyclic Polymers via the Ring-Expansion Polymerization of Macrocycles with a Bis(hindered amino)disulfide Linker, Macromolecules, 2021, 54, 8154-8163.

  7. R. Tsukamoto, J. Kida, D. Aoki, H. Otsuka, Post-polymerization Modification of Polybenzoxazines by Boronic Acids Supported by B-N Interactions, Polym. Chem., 2021, 12, 5266-5270.

  8. Y. Mao. Y. Mao, Y. Kubota, J. Gong, T. Kurose, A. Ishigami, K. Seshimo, T. Watabe, D. Aoki, H. Otsuka, H. Ito, Mechanical Performance and Visual Fracture Warning Function of Mechanochromic Stimuli-recovery Polymer Networks, Macromolecules, 2021, 54, 8664-8674.

  9. T. Yamamoto, D. Aoki, H. Otsuka, Polystyrene Functionalized with Diarylacetonitrile for the Visualization of Mechanoradicals and Improved Thermal Stability, ACS Macro Lett., 2021, 10, 744-748.

  10. S. Kato, D. Aoki, K. Oikawa, K. Tsuchiya, K. Numata, H. Otsuka, Visualization of the Necking Initiation and Propagation Processes duringUniaxialTensileDeformationofCrystallinePolymerFilmsvia the Generation of Fluorescent Radicals, ACS Macro Lett., 2021, 10, 623-627.

  11. J. Kida, D. Aoki, H. Otsuka, Mechanophore activation enhanced by hydrogen bonding of diarylurea motifs: An efficient supramolecular force‐transducing system, Aggregate, 2021, 2, e50.

  12. S. Kato, D. Aoki, H. Otsuka, Toughening of Polymer Networks by Freezing-induced Monomer Insertion, Chem. Lett., 2021, 50, 1223-1225.

  13. J. Kida, D. Aoki, H. Otsuka, Self-Strengthening of Cross-Linked Elastomers via the Use of Dynamic Covalent Macrocyclic Mechanophores, ACS Macro Lett., 2021, 10, 558-563. DOI:10.1021/acsmacrolett.1c00124

  14. K. Yanada, S. Kato, D. Aoki, K. Mikami, H. Sugita, H. Otsuka, Non-symmetric Mechanophores Prepared from Radical-type Symmetric Mechanophores:Bespoken Mechanofunctional Polymers, Chem. Commun., 2021, 57, 2899-2902.c

  15. T. Watabe, D. Aoki, H. Otsuka, Enhancement of Mechanophore Activation in Mechanochromic Dendrimers by Functionalization of Their Surface, Macromolecules, 2021, 54, 1725-1731. DOI: 10.1021/acs.macromol.0c02497

  16. K. Seshimo, H. Sakai, T. Watabe, D. Aoki, H. Sugita, K. Mikami, Y. Mao, A. Ishigami, S. Nishitsuji, T. Kurose, H. Ito, H. Otsuka, Segmented Polyurethane Elastomers with Mechanochromic and Self-strengthening Functions, Angew. Chme. Int. Ed., 2021, 60, 8406-8409. DOI: 10.1002/anie.202015196

  17. S. Kataoka, A Tsuruoka, D Aoki, H. Otsuka, Fast and Reversible Cross-Linking Reactions of Thermoresponsive Polymers Based on Dynamic Dialkylaminodisulfide Exchange. ACS Macro Polym. Mater., 2021, in press, DOI：10.1021/acsapm.0c01205

  18. S. Kato, S. Furukawa, D. Aoki, R. Goseki, K. Oikawa, K. Tsuchiya, N. Shimada, A. Maruyama, K. Numata, and H. Otsuka, Crystallization-induced Mechanofluorescence for Visualization of Polymer Crystallization. Nat. Commun., 2021, 12, 126, DOI：10.1038/s41467-020-20366-y

  19. S. Kato, D. Aoki, and H. Otsuka, Postmodification of Polymer Networks via the Freezing-Induced Generation of Radicals. ACS Macro Polym. Mater., 2021, in press, DOI：10.1021/acsapm.0c01195

  20. D. Aoki, A rational entry to cyclic polymers via spontaneous and selective cyclization reactions, Polym. J., 2021, 53, 257-269. DOI: https://doi.org/10.1038/s41428-020-00422-6

  21. Y. Mao, T. Kubota, T. Kurose, A. Ishigami, K. Seshimo, D.Aoki, H. Otsuka, H. Ito, Energy Dissipation and Mechanoresponsive Color Evaluation of a Poly(n hexyl Methacrylate) Soft Material Enhanced by a Mechanochromic Cross-Linker with Dynamic Covalent Bonds, Macromolecules, 2020, 53, 9313-9324. DOI: doi.org/10.1021/acs.macromol.0c01770

  22. R. Takashima, M. Ohira, H. Yokochi, D. Aoki, X. Li, H. Otsuka, Characterization of N-Phenylmaleimide-terminated Poly(ethylene glycol)s and Their Application to a Tetra-arm Poly(ethylene glycol) Gel, Soft Matter, 2020, 16, 10869-10875. DOI: doi.org/10.1039/D0SM01658F

  23. T. Yamamoto, S. Kato, D. Aoki, H. Otsuka, Diarylacetnitrile as a Molecular Probe for the Detection of Polymeric Mechanoradicals in the Bulk State via a Radical Chain-transfer Mechanism, Angew. Chem. Int. Ed., 2020, in press. DOI: doi.org/10.1002/anie.202013180

  24. Y. Shoda, T. Igarashi, H. Yamashita, Y. Kitamura, S. Takata, K. Ohishi, D. Aoki, K. Tsunoda, H. Otsuka, Structural Analysis of Polybutadienes with Urethane Linkages by Small-Angle Neutron Scattering, 2021, JPS Conf. Proc., 33, 011054.

  25. K. Ishizuki, D. Aoki, H. Otsuka, Mechanochromic Polymers That Recognize the Duration of the Mechanical Stimulation via Multiple Mechanochromism, Macromol. Rapid Commun., Macromol. Rapid Commun., 2020, 41, 2000429. DOI: org/10.1002/marc.202000429

  26. H. Sakai, D. Aoki, K. Seshimo, K. Mayumi, S. Nishitsuji, T. Kurose, H. Ito, H. Otsuka, Visualization and Quantitative Evaluation of Toughening Polymer Networks by a Sacrificial Dynamic Cross-linker with Mechanochromic Properties, ACS Macro Lett., 2020, 9, 1108-1113. DOI: 10.1021/acsmacrolett.0c00321

  27. Y. Shoda, D. Aoki, K. Tsunoda, H. Otsuka, Polybutadiene Rubbers with Urethane Linkages Prepared by a Dynamic Covalent Approach for Tire Applications Polymer, 2020, 202, 122700. DOI: 10.1016/j.polymer.2020.122700

  28. D. Aoki, M. Yanagisawa, H. Otsuka, Synthesis of Well-defined Mechanochromic Polymers Based on a Radical-Type Mechanochromophore by RAFT Polymerization: Living Radical Polymerization from a Polymerization Inhibitor, Polym. Chem., 2020, 11, 4290-4296. DOI: doi.org/10.1039/D0PY00590H

  29. R. Takashima, D. Aoki, H. Otsuka, Rational Entry to Cyclic Polymers via Thermally Induced Radical Ring-Expansion Polymerization of Macrocycles with one Bis(hindered amino)disulfide Linkage, Macromolecules, 2020, 53, 4670-4677. DOI: 10.1021/acs.macromol.0c00798

  30. T. Kureha, S. Hiroshige, D. Suzuki, J. Sawada, D. Aoki, T. Takata, M. Shibayama, Quantification for the Mixing of Polymers on Microspheres in Waterborne Latex Films, Langmuir, 2020, 36, 4855-4862. DOI: doi.org/10.1021/acs.langmuir.0c00612

  31. H. Yokochi, R. Takashima, D. Aoki, H. Otsuka, Using the Dynamic Behavior of Macrocyclic Monomers with a Bis(hindered amino)disulfide Linker for the Preparation of End-functionalized Polymers, Polym. Chem., 2020, 11, 3357-3363. DOI: 10.1039/D0PY00366B

  32. Y. Ito, D. Aoki, H. Otsuka, Functionalization of Amine-cured Epoxy Resins by Boronic Acids Based on Dynamic Dioxazaborocane Formation, Polym. Chem., 2020, 11, 5356-5364. DOI: 10.1039/d0py00048e

  33. Y. Lu, D. Aoki, J. Sawada, T. Kosuge, H. Sogawa, H. Otsuka, T. Takata, Visualization of Slide-ring Effect: A Study on Movable Cross-Linking Points Using Mechanochromism, Chem. Commun., 2020, 56, 3361-3364. DOI: 10.1039/D0CC00676A

  34. N. Tsurumi, R. Takashima, D. Aoki, S. Kuwata, H. Otsuka, A Strategy toward Cyclic Topologies Based on the Dynamic Behavior of a Bis(hindered amino)disulfide Linker, Angew. Chem. Int. Ed., 2020, 59, 4294-4298. DOI: org/10.1002/anie.201910722

  35. A. Tsuruoka, A. Takahashi, D. Aoki, H. Otsuka, Fusion of Different Cross-linked Polymers Based on Dynamic Disulfide Exchange, Angew. Chem. Int. Ed., 2020, 59, 4269-4273. DOI: org/10.1002/anie.201913430

  36. K. Kawasaki, D. Aoki, H. Otsuka, Diarylbiindolinones as Substituent-Tunable Mechanochromophores and Their Application in Mechanochromic Polymers, Macromol. Rapid Commun., 2020, 41, 1900460-1900464. DOI: org/10.1002/marc.201900460

  37. J. Sawada, D. Aoki, Y. Sun, K. Nakajima, T. Takata, Effect of Co-Existing Covalent Cross-Links on The Properties of Rotaxane-Cross-Linked Polymers, ACS Applied Polymer Materials, 2020, 2, 1061-1064. DOI: org/10.1021/acsapm.9b00994

  38. F. Hoshino, T. Kosuge, D. Aoki, H. Otsuka, Mechanofluorescent polymer/silsesquioxane composites based on tetraarylsuccinonitrile, Mater. Chem. Front., 2019, 3, 2681-2685, DOI: 10.1039/C9QM00535H

  39. B. J. Ree, D. Aoki, J. Kim, T. Satoh, T. Takata, M. Ree, Macromolecular [2]Rotaxanes Linked with Polystyrene: Properties and Nanoscale Film Morphologies, Macromolecules, 2019, 52, 5325-5336, DOI: marc.201900334R1

  40. R. Takashima, J. Kida, D. Aoki, H. Otsuka, Maleimidophenyl Isocyanates as Post-polymerization Modification Agents and Their Applications in the Synthesis of Block Copolymers, J. Polym. Sci., Part A: Polym. Chem., 2019, 57, 2396?2406, DOI: doi.org/10.1002/pola.29450

  41. B. J. Ree, D. Aoki, J. Kim, T. Satoh, T. Takata, M. Ree, Phase Transition Behaviors and Nanoscale Film Morphologies of Poly(δ-valerolactone) Axles Bearing Movable and Fixed Rotaxane Wheels, Macromolecular Rapid Communications, 2019, 40, 1900334-1900343, DOI: doi.org/10.1002/marc.201900334

  42. K. Yamada, D. Aoki, K. Nakazono, T. Takata, Sulfur-33 NQR investigation of the electric-field-gradient tensor in an organosulfur compound, Verlag der Zeitschrift fur Naturforschung B, 2019, 74, 421-425. DOI: https://doi.org/10.1515/znb-2019-0003

  43. T. Kosuge, D. Aoki, H. Otsuka, Network Reorganization in Cross-linked Polymer/silica Composites Based on Exchangeable Dynamic Covalent Carbon?carbon Bonds, Polymer, 2019, 177, 10-18, DOI: 10.1016/j.polymer.2019.05.046

  44. T. Watabe, K. Ishizuki, D. Aoki, H. Otsuka, Mechanochromic Dendrimers: The Relationship between Primary Structure and Mechanochromic Properties in the Bulk, Chem. Commun., 2019, 55, 6831-6834, DOI: 10.1039/C9CC03011E

  45. S. Hiroshige, J. Sawada, D. Aoki, T. Takata, D. Suzuki, Investigation of Mechanical Properties of Latex Films Prepared from Poly (Butyl Acrylate-co-Methyl Methacrylate) Microspheres Crosslinked with Rotaxane, J. Soc. Rheol. Japan, 2019, 47, 051-054.

  46. S. Kato, D. Aoki, H. Otsuka, Introducing Static Cross-linking Points into Dynamic Covalent Polymer Gels That Display Freezing-induced Mechanofluorescence: Enhanced Force Transmission Efficiency and Stability, Polymer Chemistry, 2019, 10, 2636-2640, DOI: 10.1039/c9py00204a

  47. J. Sawada, D. Aoki, T. Takata, A vinylic rotaxane cross-linker containing crown ether for hydrophilic and hard rotaxane-networked polymers, Macromol. Symp., 2019, 385, 1800186-1800191, DOI: masy.201800186

  48. K. Iijima, D. Aoki, T. Takata, Syntheses and Property of Rotaxane-Cross-linked Polymers: Influence of Coexisted Covalent Cross-link on The Property, Nippon Gomu Kyokaishi, 2019, 92, 101-108.

  49. T. Kosuge, X. Zhu, V. M. Lau, D. Aoki, T. J. Martinez, J. S. Moore, H. Otsuka, Multicolor Mechanochromism of a Polymer/Silica Composite with Dual Distinct Mechanophores, J. Am. Chem. Soc., 2019, 141, 1989-1902, DOI: 10.1021/jacs.8b13310

  50. J. Sawada, D. Aoki, H. Otsuka, T. Takata, A Guiding Principle for Toughening Cross-Linked Polymers: Synthesis and Application of Mobility-Controlling Rotaxane Cross-Linkers, Angew. Chem. Int. Ed., 2019, 58, 2765-2768, DOI: 10.1002/anie.201813439

  51. J. Kida, D. Aoki, H. Otsuka, Photo-induced Regulation of the Heat Resistance in Polymer Networks with Diarylethene-conjugated Reversible Covalent Cross-links, ACS Macro Lett., 2019, 8, 1-6, DOI: 10.1021/acsmacrolett.8b00876

  52. H. Sakai, T. Sumi, D. Aoki, R. Goseki, H. Otsuka, Thermally Stable Radical-type Mechanochromic Polymers Based on Difluorenylsuccinonitrile, ACS Macro Lett., 2018, 7, 1359-1363, DOI: 10.1021/acsmacrolett.8b00755

  53. Y. Ito, J. Kida, D. Aoki, H. Otsuka, Modification of Amine-cured Epoxy Resins by Boronic Acids Based on Their Reactivity with Intrinsic Diethanolamine Units, Chem. Commun, 2018, 54, 12930-12933. DOI: 10.1039/C8CC07412G

  54. J. Kida, K. Imato, D. Aoki, R. Goseki, M. Morimoto, H. Otsuka, The Photoregulation of a Mechanochemical Polymer Scission, Nat. Commun., 2018, 9, 3504-3509, DOI: 10.1038/s41467-018-05996-7

  55. S. Kato, K. Ishizuki, D. Aoki, R. Goseki, H. Otsuka, Freezing-Induced Mechanoluminescence of Polymer Gels, ACS Macro Lett., 2018, 7,1087-1091. DOI: 10.1021/acsmacrolett.8b00521

  56. K. Ishizuki, D. Aoki, R. Goseki, H. Otsuka, Multicolor Mechanochromic Polymer Blends That Can Discriminate between Stretching and Grinding, ACS Macro Lett., 2018, 7, 556-560. DOI: 10.1021/acsmacrolett.8b00224

  57. K. Ishizuki, H. Oka, D. Aoki, R. Goseki, Hideyuki Otsuka, Mechanochromic Polymers That Turn Green Upon the Dissociation of Diarylbibenzothiophenonyl: The Missing Piece toward Rainbow Mechanochromism, Chem. Eur. J., 2018, 24, 3170 ? 3173 DOI: 10.1002/chem.201800194

  58. H. Sato, D. Aoki, T. Takata,　The 3,5-Dimethylphenyl or the 2,6-Dimethylphenyl Group? Development of Size-Complementary Molecular and Macromolecular [2]Rotaxanes, Chem. Asian J., 2018, 13, 785-789. doi.org/10.1002/asia.20180017

  59. M. Ogawa, H. Sogawa, S. Mizuno, D. Aoki, T. Takata, Chemoselective Suzuki Coupling of Bromoarenes Catalysed by Palladium(II)-Complexing Macrocycles in Aqueous Media, ChemistrySelect, 2018, 3, 446-450. DOI: 10.1002/slct.201703073

  60. T. Takata, D. Aoki Topology-Transformable Polymer: Linear?Branched Polymer Structure Change Utilizing Mechanical Linking of Polymer Chains, Polym. J., 2018, 50, 127?147. DOI: 10.1038/pj.2017.60.

  61. T. Kureha, D. Aoki, S. Hiroshige, K. Iijima, D. Aoki, T. Takata, D. Suzuki, Decoupled Thermo- and pH-responsive Hydrogel Microspheres Cross-linked by Rotaxane Networks, Angew. Chem., Int. Ed., 2017, 556, 15393-15396, DOI: 10.1002/anie.201709633

  62. D. Aoki, T. Takata, Mechanically linked supramolecular polymer architectures derived from macromolecular [2]rotaxanes: Synthesis and topology transformation, Polymer, 2017, 128, 276?296. doi.org/10.1016/j.polymer.2017.08.020

  63. S. Hiroshige, T. Kureha, D. Aoki, J. Sawada, D. Aoki, T. Takata, D. Suzuki, Formation of Tough Films by Evaporation of Water from Dispersions of Elastomer Microspheres Crosslinked with Rotaxane Supramolecules, Chem. Eur. J., 2017, 23, 8405 ?8408. DOI: 10.1002/chem.201702077

  64. J. Sawada, D. Aoki, T. Takata, Vinylic Rotaxane Cross-Linker Comprising Different Axle Length for the Characterization of Rotaxane Cross-linked Polymers, Macromol. Symp., 2017, 372, 115?119. DOI: 10.1002/masy.201600160

  65. D. Aoki, G. Aibara, S. Uchida, T. Takata, A Rational Entry to Cyclic Polymers via Selective Cyclization by Self-Assembly and Topology Transformation of Linear Polymers, J. Am. Chem. Soc., 2017, 139, 6791?6794. DOI: 10.1021/jacs.7b01151

  66. J. Sawada, D. Aoki, M. Kuzume, K. Nakazono, S. Uchida, H. Otsuka, and T. Takata, A vinylic rotaxane cross-linker for toughened network polymers from the radical polymerization of vinyl monomers, Polym. Chem., 2017, 8, 1878-1881. DOI: 10.1039/C7PY00193B

  67. K. Iijima, D. Aoki, H. Otsuka, T. Takata, Synthesis of Rotaxane Cross-linked Polymers with Supramolecular Cross-linkers Based on γ-CD and PTHF Macromonomers: The Effect of the Macromonomer Structure on the Polymer Properties, Polymer, 2017, 128, 392?396. DOI:10.1016/j.polymer.2017.01.024

  68. H. Sato, D. Aoki, T. Takata, Synthesis and Star/Linear Topology Transformation of a Mechanically Linked ABC Terpolymer, ACS Macro Lett., 2016, 5, 699-703. DOI: 10.1021/acsmacrolett.6b00320

  69. K. Iijima, D. Aoki, H. Sogawa, S. Asai, T. Takata, Synthesis and Characterization of Supramolecular Cross-linkers Containing Cyclodextrin Dimer and Trimer, Polym. Chem., 2016, 7, 3492-3495. DOI: 10.1039/C6PY00367B

  70. S. Valentina, T. Ogawa, K. Nakazono, D. Aoki, T. Takata, Efficient Synthesis of Cyclic Block Copolymer by Rotaxane Protocol via Linear-Cyclic Topology Transformation, Chem. Eur. J., 2016, 22, 8759-8762. DOI: 10.1002/chem.201601266

  71. Z. Chen, D. Aoki, S. Uchida, H, Marubayashi, S, Nojima, T. Takata, Effect of Component Mobility on the properties of Macromolecular [2]Rotaxanes, Angew. Chem., Int. Ed., 2016, 55, 2778-2781. DOI: 10.1002/ange.201510953

  72. J. Sawada, D. Aoki, S. Uchida, H, Otsuka, T. Takata, Synthesis of vinylic macromolecular rotaxane cross-linkers endowing network polymers with toughness, ACS Macro Lett., 2015, 4, 598-601. DOI: 10.1021/acsmacrolett.5b00242

  73. K. Yamada, D. Aoki, K. Kitagawa, T. Takata, Frequency-swept solid-state 33S NMR of an organosulfur compound in an extremely low magnetic field, Chemical Physics Letters, 2015, 630, 86-90. DOI: 10.1016/j.cplett.2015.04.040

  74. D. Aoki, S. Uchida, T. Takata, Star/Linear Polymer Topology Transformation Facilitated by Mechanical Linking of Polymer chains, Angew. Chem., Int. Ed., 2015, 54, 6770-6774. DOI: 10.1002/anie.201500578

  75. T. Ogawa, K. Nakazono, D. Aoki, S. Uchida, T. Takata, Effective Approach to Cyclic Polymer from Linear Polymer: Synthesis and Transformation of Macromolecular [1]rotaxane, ACS Macro Lett., 2015, 4, 343-347. DOI: 10.1021/acsmacrolett.5b00067

  76. D. Aoki, S. Uchida, T. Takata, Synthesis and Charactarization of a Mechanically linked Transformable Polymer, Polym. J., 2014, 46, 546-552. DOI: 10.1038/pj.2014.22

  77. D. Aoki, S. Uchida, T. Takata, Mechanically linked Block/Graft Copolymers: Effective Synthesis via Functional Macromolecular [2]rotaxanes, ACS Macro Lett., 2014, 3, 324-328. DOI: 10.1021/mz5001306

  78. D. Aoki, S. Uchida, K. Nakazono, Y. Koyama, T. Takata, Macromolecular [2]Rotaxanes: Effective Synthesis and Characterization, ACS Macro Lett., 2013, 2, 461-465. DOI: 10.1021/mz400197d

解説記事

  1. 青木大輔、飛翔する若手研究者,日本化学会機関誌「化学と工業」 2021年10月号

  2. 大塚英幸、青木大輔、庄田靖宏、角田克彦、 動的共有結合化学を利用した自己修復性高分子および新規高付加価値ウレタン含有ジエン系ゴム材料の設計, 日本ゴム協会誌 2021, 94巻 No 2, 33-38.

  3. 青木大輔、高嶋力任、大塚英幸 p-位にマレイミド構造を持つフェニルイソシアネート誘導体を用いた高分子修飾とその応用,ネットワークポリマー論文集 2021,42,30-37.

  4. 大塚英幸、青木大輔、 高分子反応を利用したメカノクロミックポリマー, 会誌「高分子」, 2020, 69, 515-517.

  5. Daisuke Aoki, Hideyuki Otsuka, Mechanochrimic Polymers as Stress-sensing Soft Materials, Mechanically Responsive Materials for Soft Robotics (Edited by Hideko Koshima), 2019, 307-325.

  6. 動的共有結合ポリマー、日本化学会 編 CSJカレントレビュー　超分子ポリマー　大塚英幸, 青木大輔、化学同人,2019,82-90.

  7. 注目の論文「フラストレイティドLweisペア付加体　可逆性が生みだす自己修復性ゲル “Frustrated Lewis Pair Polymers as Responsive Self-Healing gels”」M. Wang, F. Nudelman, R. R Matthes, M. P. Shaver, J. Am. Chem. Soc.,2017, 139, 14232.に関する解説　青木大輔, 化学, 2018,73,5月号 62.

  8. 高分子鎖の可動な連結を利用するトポロジー変換と特性制御　（特集　高分子の形の制御）高田 十志和, 青木 大輔, 高分子 / High polymers, Japan : polymers 2017, 66, 217-219.

  9. 高分子鎖の機械的な連結による分岐￢-線状トポロジー変換　青木 大輔, 高田 十志和, 日本ゴム協会誌,2017, 90, 283-289.

  10. 新しい架橋剤:空間連結型架橋剤の合成とビニル重合系への展開, 打田 聖, 澤田 隼, 飯島 圭祐、青木大輔, 中薗和子、高田十志和, 高分子論文集, 2015, 72, 93-103.

　　
　　　　　

バナースペース

大塚研究室　OTSUKA LAB

〒152-8550
東京都目黒区大岡山2-12-1　
東京工業大学
物質理工学院　応用化学系

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