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Institute of Science Tokyo

OTSUKA LABORATORY

研究業績ACHIEVEMENT

　　　　　 　　

論文 -ORIGINAL PAPER-

  1. TBA
    W. KHAWDAS, R. IIJIMA, K. ONUMA, H. OTUSKA, H. ITO
    Macromolecules, (2025), in press.
    DOI: 未定

  2. Triazolinedione-functionalized Isoprene Rubber Composites with self-adhesion via Cross-linking with Zinc Dimethacrylate
    K. KOTANI, Y. KITAMURA, K. TSUNODA, A. TAKAHASHI, H. OTSUKA
    RSC Appl. Polym., 3, 347-360 (2025).
    DOI: 10.1039/D4LP00331D

  3. Multicolor Mechanochromic Polymer Blends That Can Distinguish between Tensile–Stress States
    K. ISHIZUKI, A. TAKAHASHI, H. OTSUKA
    Macromol. Rapid Commun., 46, 2400812 (2025).
    DOI: 10.1002/marc.202400812

  4. Reversible Modulation of Polymer Chain Mobility by Selective Cage Opening and Closing of Pendant Boratrane Units
    A. TAKAHASHI, M. YAMANISHI, A. KAMEYAMA, H. OTSUKA
    Polym. J., 57, 259-268 (2025).
    DOI: 10.1038/s41428-024-00986-7

  5. Visualization of Polymer Chain Scission During Melt Processing Using a Mechanochromic Probe
    W. KHAWDAS, Y. KUBOTA, T. YAMAMOTO, H. OTSUKA, H. ITO
    Macromolecules, 7245-7252 (2024).
    DOI: 10.1021/acs.macromol.3c02182

  6. Direct and Reversible Transformations between Intermolecular Polymer Networks and Single-Chain Nanoparticles Based on Thermally Dissociable Bis(hindered amino)disulfide Linkages
    G. TOMONO, H. YOKOCHI, A. TAKAHASHI, D. AOKI, H. OTSUKA
    Macromolecules, 57, 6362-6369 (2024).
    DOI: 10.1021/acs.macromol.4c00359

  7. Diverse Metastable Diarylacetonitrile Radicals Generated by Polymer Mechanochemistry
    T. YAMAMOTO, D. AOKI, K. MIKAMI, H. OTSUKA
    RSC Mechanochemistry, 1, 181-188 (2024).
    DOI: 10.1039/D3MR00031A

  8. Visualization of Mechanochemical Polymer-chain Scission in Double-network Elastomers Using a Radical-transfer-type Fluorescent Molecular Probe
    T. YAMAMOTO, A. TAKAHASHI, H. OTSUKA
    RSC Mechanochemistry, 1, 63-68 (2024).
    DOI: 10.1039/D3MR00016H

  9. Self-healing and Shape-memory Polymers Based on Cellulose Acetate Matrix
    H. JIA, K. JIMBO, H. YOKOCHI, H. OTSUKA, T. MICHINOBU,
    Sci. Tech. Adv. Mater., 25, 2320082 (2024).
    DOI: 10.1080/14686996.2024.2320082

  10. A Thermally Driven Rotaxane–Catenane Interconversion with a Dynamic Bis(hindered amino)disulfide
    R. TAKASHIMA, D. AOKI, A. TAKAHASHI, H. OTSUKA
    Org. Biomol. Chem., 22, 927-931 (2024).
    DOI: 10.1039/D3OB01693E

  11. A Sacrificial Mechanical Bond is as Effective as a Sacrificial Covalent Bond in Increasing Cross-Linked Polymers Toughness
    H. YOKOCHI, R. O’NEILL, T. ABE, D. AOKI, R. BOULATOV, H. OTSUKA
    J. Am. Chem. Soc., 145, 23794-23801 (2023).
    DOI: 10.1021/jacs.3c08595

  12. Tough Tetrazine-functionalized Styrene–butadiene Rubber with Self-adhesion through Zinc-nitrogen Coordination
    K. KOTANI, K. TSUNODA, H. OTSUKA
    RSC Appl. Polym., 1 229-242 (2023).
    DOI: 10.1039/D3LP00112A

  13. Ring–Chain Equilibria of Dynamic Macrocycles with a Bis(hindered amino)disulfide Linker
    R. TAKASHIMA, D. AOKI, S. KUWATA, H. OTSUKA
    Polym. Chem., 14, 4344-4351 (2023).
    DOI: 10.1039/D3PY00808H

  14. A Rational Design Strategy of Radical-type Mechanophores with Thermal Tolerance
    Y. LU, H. SUGITA, K. MIKAMI, D. AOKI, H. OTSUKA
    Chem. Sci., 14, 8792-8797 (2023).
    DOI: 10.1039/D3SC02991C

  15. Maleimidophenyl Isocyanates Adducts as Versatile Post-polymerization Modification Agents for Biobased Furan Polymers
    R. TAKASHIMA, D. AOKI, H. OTSUKA
    J. Polym. Sci., 61 2076-2073 (2023).
    DOI: 10.1002/pol.20230316

  16. Efficient detection of polymeric mechanoradicals via fluorescent molecular probes stabilized by steric hindrance
    T. YAMAMOTO, H. OTSUKA
    Polym. Chem., 14, 2464-2468 (2023).
    DOI: 10.1039/d3py00296a

  17. Plastics to Fertilizer: Guiding Principles for Functionable and Fertilizable Fully Bio-based Polycarbonates
    T. ABE, T. KAMIYA, D. AOKI, H. OTSUKA
    Polym. Chem., 14, 2469-2477 (2023).
    DOI: 10.1039/d3py00079f

  18. Theoretical and Experimental Investigations of Stable Arylfluorene-based Radical-type Mechanophores
    H. SUGITA, Y. LU, D. AOKI, H. OTSUKA, K. MIKAMI,
    Chem. Eur. J., 29, e2022032 (2023).
    DOI: 10.1002/chem.202203249

  19. Swelling-induced Mechanochromism in Multinetwork Polymers
    T. Watabe, H. OTSUKA,
    Angew. Chem. Int. Ed., 62, e202216469 (2023).
    DOI: 10.1002/anie.202216469

  20. Isolation of Hetero-telechelic Polyethylene Glycol with Groups of Different Reactivity at the Chain Ends
    T. SATO, R. TAKASHIMA, D. AOKI, H. OTSUKA,
    Polym. J., 54, 1321-1329 (2022).
    DOI: 10.1038/s41428-022-00676-2

  21. Polymer-Network Toughening and Highly Sensitive Mechanochromism via a Dynamic Covalent Mechanophore and a Multinetwork Strategy
    T. Watabe, D. AOKI, H. OTSUKA,
    Macromolecules, 55, 5795-5802 (2022).
    DOI: 10.1021/acs.macromol.2c00724

  22. Structure Reconfigurable Mechanochromic Polymer with Shape Memory and Strain-Monitored Function Enabled by a Covalent Adaptable Network
    Y. MAO, Y. KUBOTA, R. FENG, J. GONG, A. ISHIGAMI, Y. KOBAYASHI, T. WATABE, D. AOKI, H. OTSUKA, H. ITO,
    Macromolecules, 55, 3948-3957 (2022).
    DOI: 10.1021/acs.macromol.2c00529

  23. Mechanochromic Elastomers with Different Thermo- and Mechano-responsive Radical-type Mechanophores
    K. YANADA, D. AOKI, H. OTSUKA,
    Soft Matter, 18, 3218-3225 (2022).
    DOI: 10.1039/D1SM01786A

  24. Enhancement of Mechanophore Activation by Electrostatic Interaction
    R. KASORI, T. WATABE, D. AOKI, H. OTSUKA,
    Bull. Chem. Soc. Jpn., 95, 645-651 (2022).
    DOI: 10.1246/bcsj.20220021

  25. Mechanochromic Cyclodextrins
    Y. SUGITA, D. AOKI, H. OTSUKA, M. TOKITA,
    Chem. Commun., 58, 3067-3070 (2022).
    DOI: 10.1039/D2CC00363E

  26. Plastics to Fertilizers: Chemical Recycling of a Bio-based Polycarbonate as a Fertilizer Source
    T. ABE, R. TAKASHIMA, T. KAMIYA, C. P. FOONG, K. NUMATA, D. AOKI, H. OTSUKA,
    Green Chem., 23, 9030-9037 (2021).
    DOI: 10.1039/d1gc02327f

  27. Mechanochemical Reactions of Bis(9-methylphenyl-9-fluorenyl) Peroxides and Their Applications in Cross-Linked Polymers
    Y. LU, H. SUGITA, K. MIKAMI, D. AOKI, H. OTSUKA,
    J. Am. Chem. Soc., 143, 17744-17750 (2021).
    DOI: 10.1021/jacs.1c08533

  28. Effect of Bulky 2,6-Bis(spirocyclohexyl)-Substituted Piperidine Rings in Bis(hindered amino)trisulfide on Thermal Healability of Polymethacrylate Networks
    M. AIBA, T. KOIZUMI, K. OKAMOTO, M. YAMANAKA, M. FUTAMURA, Y. ISHIGAKI, M. ODA, C. OOKA, A. TAKAHASHI, H. OTSUKA,
    Mater. Adv., 2, 7709-7714 (2021).
    DOI: 10.1039/D1MA00811K

  29. Topology Transformation toward Cyclic, Figure-Eight-Shaped, and Cross-Linked Polymers Based on the Dynamic Behavior of a Bis(hindered amino)disulfide Linker
    H. YOKOCHI, M. OHIRA, M. OKA, S. HONDA, X. Li, D. AOKI, H. OTSUKA,
    Macromolecules, 54, 9992-10000 (2021).
    DOI: 10.1021/acs.macromol.1c01437

  30. Synthetic Strategy for Mechanically Interlocked Cyclic Polymers via the Ring-Expansion Polymerization of Macrocycles with a Bis(hindered amino)disulfide Linker
    R. TAKASHIMA, D. AOKI, H. OTSUKA
    Macromolecules, 54, 8154-8163 (2021).
    DOI: 10.1021/acs.macromol.1c01067

  31. Post-polymerization Modification of Polybenzoxazines by Boronic Acids Supported by B?N Interactions
    R. TSUKAMOTO, J. KIDA, D. AOKI, H. OTSUKA
    Polym. Chem., 12, 5266-5270 (2021).
    DOI: 10.1039/D1PY00657F

  32. Mechanical Performance and Visual Fracture Warning Function of Mechanochromic Stimuli-recovery Polymer Networks
    Y. MAO, Y. KUBOTA, J. GONG, T. KUROSE, A. ISHIGAMI, K. SESHIMO, T. WATABE, D. AOKI, H. OTSUKA, H. ITO
    Macromolecules, 54, 8664-8674 (2021).
    DOI: 10.1021/acs.macromol.1c00904

  33. Polystyrene Functionalized with Diarylacetonitrile for the Visualization of Mechanoradicals and Improved Thermal Stability
    T. YAMAMOTO, D. AOKI, H. OTSUKA
    ACS Macro Lett., 10, 744-748 (2021).
    DOI: 10.1021/acsmacrolett.1c00352

  34. Visualization of the Necking Initiation and Propagation Processes during Uniaxial Tensile Deformation of Crystalline Polymer Films via the Generation of Fluorescent Radicals
    S. KATO, D. AOKI, K. OIKAWA, K. TSUCHIYA, K. NUMATA, H. OTSUKA
    ACS Macro Lett., 10, 623-627 (2021).
    DOI: 10.1021/acsmacrolett.1c00185

  35. Mechanophore Activation Enhanced by Hydrogen Bonding of Diarylurea Motifs: An Efficient Supramolecular Force‐transducing System
    J. KIDA, D. AOKI, H. OTSUKA
    Aggregate, 2, e50 (2021).
    DOI: 10.1002/agt2.50

  36. Toughening of Polymer Networks by Freezing-induced Monomer Insertion
    S. KATO, D. AOKI, H. OTSUKA
    Chem. Lett., 50, 1223-1225 (2021).
    DOI: 10.1246/cl.210142

  37. Self-Strengthening of Cross-Linked Elastomers via the Use of Dynamic Covalent Macrocyclic Mechanophores
    J. KIDA, D. AOKI, H. OTSUKA
    ACS Macro Lett., 10, 558-563 (2021).
    DOI: 10.1021/acsmacrolett.1c00124

  38. Enhancement of Mechanophore Activation in Mechanochromic Dendrimers by Functionalization of Their Surface
    T. WATABE, D. AOKI, H. OTSUKA
    Macromolecules, 54, 1725-1731 (2021).
    DOI: 10.1021/acs.macromol.0c02497

  39. Non-symmetric Mechanophores Prepared from Radical-type Symmetric Mechanophores: Bespoken Mechanofunctional Polymers
    K. YANADA, S. KATO, D. AOKI, K. MIKAMI, H. SUGITA, H. OTSUKA
    Chem. Commun., 57, 2899-2902 (2021).
    DOI: 10.1039/D0CC08048A

  40. Segmented Polyurethane Elastomers with Mechanochromic and Self-strengthening Functions
    K. SESHIMO, H. SAKAI, T. WATABE, D. AOKI, H. SUGITA, K. MIKAMI, Y. MAO, A. ISHIGAMI, S. NISHITSUJI, T. KUROSE, H. ITO, H. OTSUKA
    Angew. Chem. Int. Ed., 60 8406-8409 (2021).
    DOI: 10.1002/anie.202015196

  41. Fast and Reversible Cross-Linking Reactions of Thermoresponsive Polymers Based on Dynamic Dialkylaminodisulfide Exchange
    S. KATAOKA, A. TSURUOKA, D. AOKI, H. OTSUKA
    ACS Appl. Polym. Mater., 3, 888-895 (2021).
    DOI: 10.1021/acsapm.0c01205

  42. Crystallization-induced Mechanofluorescence for Visualization of Polymer Crystallization
    S. KATO, S. FURUKAWA, D. AOKI, R. GOSEKI, K. OIKAWA, K. TSUCHIYA, N. SHIMADA, A. MARUYAMA, K. NUMATA, H. OTSUKA
    Nat. Commun., 12, 126 (2021).
    DOI: 10.1038/s41467-020-20366-y

  43. Postmodification of Polymer Networks via the Freezing-Induced Generation of Radicals
    S. KATO, D. AOKI, H. OTSUKA,
    ACS Appl. Polym. Mater., 3, 594-598 (2021).
    DOI: 10.1021/acsapm.0c01195

  44. A Diarylacetonitrile as a Molecular Probe for the Detection of Polymeric Mechanoradicals in the Bulk State through a Radical Chain-Transfer Mechanism
    T. YAMAMOTO, S. KATO, D. AOKI, H. OTSUKA
    Angew. Chem. Int. Ed., 60 2680-2683 (2021).
    DOI: 10.1002/anie.20201318

  45. Mechanochromic Polymers That Recognize the Duration of the Mechanical Stimulation via Multiple Mechanochromism
    K. ISHIZUKI, D. AOKI, H. OTSUKA
    Macromol. Rapid Commun., 42, 2000429 (2021).
    DOI: 10.1002/marc.202000429

  46. Characterization of N-Phenylmaleimide-terminated Poly(ethylene glycol)s and Their Application to a Tetra-arm Poly(ethylene glycol) Gel
    R. TAKASHIMA, M. OHIRA, H. YOKOCHI, D. AOKI, X. LI, H. OTSUKA
    Soft Matter, 16, 10869-10875 (2020).
    DOI: 10.1039/d0sm01658f8

  47. Energy Dissipation and Mechanoresponsive Color Evaluation of a Poly(n hexyl Methacrylate) Soft Material Enhanced by a Mechanochromic Cross-Linkerwith Dynamic Covalent Bonds
    Y. MAO, T. KUBOTA, T. KUROSE, A. ISHIGAMI, K. SESHIMO, D.AOKI, H. OTSUKA, H. ITO
    Macromolecules, 53, 9313-9324 (2020).
    DOI: 10.1021/acs.macromol.0c01770

  48. Use of Bis(2,2,6,6-tetramethylpiperidin-1-yl)trisulfide as a Dynamic Covalent Bond for Thermally Healable Crosslinked Polymer Network
    M. AIBA, T. KOIZUMI, M. FUTAMURA, K. OKAMOTO, M. YAMANAKA, Y. ISHIGAKI, M. ODA, C. OOKA, A. TSURUOKA, A. TAKAHASHI, H. OTSUKA.
    ACS Appl. Polym. Mater. 2, 4054-4061 (2020)
    DOI: 10.1021/acsapm.0c00681

  49. Visualization and Quantitative Evaluation of Toughening Polymer Networks by a Sacrificial Dynamic Cross-linker with Mechanochromic Properties
    H. SAKAI, D. AOKI, K. SESHIMO, K. MAYUMI, S. NISHITSUJI, T. KUROSE, H. ITO, H. OTSUKA
    ACS Macro Lett., 9, 1108-1113 (2020).
    DOI: 10.1021/acsmacrolett.0c00321

  50. Polybutadiene Rubbers with Urethane Linkages Prepared by a Dynamic Covalent Approach for Tire Applications
    Y. SHODA, D. AOKI, K. TSUNODA, H. OTSUKA
    Polymer, 202, 122700 (2020).
    DOI: 10.1016/j.polymer.2020.122700

  51. Structural Reorganization and Crack-healing Properties of Hydrogels Based on Dynamic Diselenide Linkages
    H. XU, N. SUZUKI, A. TAKAHASHI, T. OHISHI, R. GOSEKI, X.-M. XIE, H. OTSUKA
    Sci. Tech. Adv. Mater., 21, 450-460 (2020).
    DOI: 10.1080/14686996.2020.1783967

  52. Synthesis of Well-defined Mechanochromic Polymers Based on a Radical-Type Mechanochromophore by RAFT Polymerization: Living Radical Polymerization from a Polymerization Inhibitor
    D. AOKI, M. YANAGISAWA, H. OTSUKA,
    Polym. Chem., 11, 4290-4296 (2020).
    DOI: 10.1039/D0PY00590H

  53. Rational Entry to Cyclic Polymers via Thermally Induced Radical Ring-Expansion Polymerization of Macrocycles with one Bis(hindered amino)disulfide Linkage
    R. TAKASHIMA, D. AOKI, H. OTSUKA
    Macromolecules, 53, 4670-4677 (2020).
    DOI: 10.1021/acs.macromol.0c00798

  54. Using the Dynamic Behavior of Macrocyclic Monomers with a Bis(hindered amino)disulfide Linker for the Preparation of End-functionalized Polymers
    H. YOKOCHI, R. TAKAS HIMA, D. AOKI, H. OTSUKA
    Polym. Chem., 11, 3557-3563 (2020)
    DOI: 10.1039/D0PY00366B

  55. Segmented Polyurethanes Containing Movable Rotaxane Units on the Main Chain: Synthesis, Structure, and Mechanical Properties
    J. SAWADA, H. SOGAWA, H. MARUBAYASHI, S. NOJIMA, H. OTSUKA, K. NAKAJIMA, Y. AKAE, T. TAKATA
    Polymer, 193, 122358 (2020).
    DOI: 10.1016/j.polymer.2020.122358

  56. Functionalization of Amine-cured Epoxy Resins by Boronic Acids Based on Dynamic Dioxazaborocane Formation
    Y. ITO, D. AOKI, H. OTSUKA
    Polym. Chem., 11, 5356-5364 (2020).
    DOI: 10.1039/D0PY00048E

  57. Visualization of Slide-ring Effect: A Study on Movable Cross-Linking Points Using Mechanochromism
    Y. LU, D.AOKI, J. SAWADA, T. KOSUGE, H. SOGAWA, H. OTSUKA, T. TAKATA
    Chem. Commun., 56, 3361-3364 (2020).
    DOI: 10.1039/C9CC09452K

  58. A Strategy toward Cyclic Topologies Based on the Dynamic Behavior of a Bis(hindered amino)disulfide Linker
    N. TSURUMI, R. TAKASHIMA, D. AOKI, S. KUWATA, H. OTSUKA
    Angew. Chem. Int. Ed., 59, 4269-4273 (2020).
    DOI: 10.1002/anie.201910722

  59. Fusion of Different Cross-linked Polymers Based on Dynamic Disulfide Exchange
    A. TSURUOKA, A. TAKAHASHI, D. AOKI, H. OTSUKA
    Angew. Chem. Int. Ed., 59, 4294-4298 (2020).
    DOI: 10.1002/anie.201913430

  60. Diarylbiindolinones as Substituent-Tunable Mechanochromophores and Their Application in Mechanochromic Polymers
    K. KAWASAKI, D. AOKI, H. OTSUKA
    Macromol. Rapid Commun., 41, 1900460 (2020).
    DOI: 10.1002/marc.201900460

  61. Mechanofluorescent Polymer/silsesquioxane Composites Based on Tetraarylsuccinonitrile
    F. HOSHINO, T. KOSUGE, D. AOKI, H. OTSUKA
    Mater. Chem. Front., 3, 2681-2685 (2019).
    DOI: 10.1039/c9qm00535h

  62. Internal Structure of Hyaluronic Acid Hydrogels Controlled by Iron(III) Ion–Catechol Complexation
    J. RYU, S. KIM, I. OH, S. KATO, T. KOSUGE, A. V. SOKOLOVA, J. LEE, H. OTSUKA, D. SOHN
    Macromolecules, 52, 6502-6513 (2019).
    DOI: 10.1021/acs.macromol.9b00889

  63. Maleimidophenyl Isocyanates as Post-polymerization Modification Agents and Their Applications in the Synthesis of Block Copolymers
    R. TAKASHIMA, J. KIDA, D. AOKI, H. OTSUKA
    J. Polym. Sci., Part A: Polym. Chem., 57, 2396-2406 (2019).
    DOI: 10.1002/pola.29450

  64. Network Reorganization in Cross-linked Polymer/silica Composites Based on Exchangeable Dynamic Covalent Carbon–carbon Bonds
    T. KOSUGE, D. AOKI, H. OTSUKA
    Polymer, 177, 10-18 (2019).
    DOI: 10.1016/j.polymer.2019.05.046

  65. Mechanochromic Dendrimers: The Relationship between Primary Structure and Mechanochromic Properties in the Bulk
    T. WATABE, K. ISHIZUKI, D. AOKI, H. OTSUKA
    Chem. Commun., 55, 6831-6834 (2019).
    DOI: 10.1039/C9CC03011E

  66. Introducing Static Cross-Linking Points into Dynamic Covalent Polymer Gels that Display Freezing-Induced Mechanofluorescence: Enhanced Force Transmission Efficiency and Stability
    S. KATO, D. AOKI, H. OTSUKA
    Polym. Chem., 10, 2636-2640 (2019).
    DOI: 10.1039/c9py00204a

  67. Multicolor Mechanochromism of a Polymer/Silica Composite with Dual Distinct Mechanophores
    T. KOSUGE, X. ZHU, V. M. LAU, D. AOKI, T. J. MARTINEZ, J. S. MOORE, H. OTSUKA
    J. Am. Chem. Soc., 141, 1989-1902 (2019).
    DOI: 10.1021/jacs.8b13310

  68. A Guiding Principle for Toughening Cross-Linked Polymers: Synthesis and Application of Mobility-Controlling Rotaxane Cross-Linkers
    J. SAWADA, D. AOKI, H. OTSUKA, T. TAKATA
    Angew. Chem. Int. Ed., 58, 2765-2768 (2019).
    DOI: 10.1002/anie.201813439

  69. Photo-induced Regulation of the Heat Resistance in Polymer Networks with Diarylethene-conjugated Reversible Covalent Cross-links
    J. KIDA, D. AOKI, H. OTSUKA
    ACS Macro Lett., 8, 1-6 (2019).
    DOI: 10.1021/acsmacrolett.8b00876

  70. Thermally Stable Radical-type Mechanochromic Polymers Based on Difluorenylsuccinonitrile
    H. SAKAI, T. SUMI, D. AOKI, R. GOSEKI, H. OTSUKA
    ACS Macro Lett., 7, 1359-1363 (2018).
    DOI: 10.1021/acsmacrolett.8b00755

  71. Modification of Amine-cured Epoxy Resins by Boronic Acids Based on Their Reactivity with Intrinsic Diethanolamine Units
    Y. ITO, J. KIDA, D. AOKI, H. OTSUKA
    Chem. Commun., 54, 12930-12933 (2018).
    DOI: 10.1039/C8CC07412G

  72. Enhancement of the Stimuli-responsiveness and Photo-stability of Dynamic Diselenide Bonds and Diselenide-containing Polymers by Neighboring Aromatic Groups
    N. SUZUKI, A. TAKAHASHI, T. OHISHI, R. GOSEKI, H. OTSUKA
    Polymer, 154, 281-290 (2018).
    DOI: 10.1016/j.polymer.2018.09.022

  73. The Photoregulation of a Mechanochemical Polymer Scission
    J. KIDA, K. IMATO, D. AOKI, R. GOSEKI, M. MORIMOTO, H. OTSUKA
    Nat. Commun., 9, 3504 (2018).
    DOI: 10.1038/s41467-018-05996-7

  74. Freezing-Induced Mechanoluminescence of Polymer Gels
    S. KATO, K. ISHIZUKI, D. AOKI, R. GOSEKI, H. OTSUKA
    ACS Macro Lett., 7,1087-1091 (2018).
    DOI: 10.1021/acsmacrolett.8b00521

  75. Multicolor Mechanochromic Polymer Blends That Can Discriminate between Stretching and Grinding
    K. ISHIZUKI, D. AOKI, R. GOSEKI, H. OTSUKA
    ACS Macro Lett., 7, 556-560 (2018).
    DOI: 10.1021/acsmacrolett.8b00224

  76. Mechanochromic Polymers that Turn Green upon the Dissociation of Diarylbibenzothiophenonyl: The Missing Piece toward Rainbow Mechanochromism
    K. ISHIZUKI, H. OKA, D. AOKI, R. GOSEKI, H. OTSUKA
    Chem. Eur. J., 24, 3170-3173 (2018).
    DOI: 10.1002/chem.201800194

  77. Thermally Healable and Reprocessable Bis(hindered amino)disulfide-Cross-Linked Polymethacrylate Networks
    A. TAKAHASHI, R. GOSEKI, K. ITO, H. OTSUKA
    ACS Macro Lett., 6, 1280-1284 (2017).
    DOI: 10.1021/acsmacrolett.7b00762

  78. Tetraarylsuccinonitriles as Mechanochromophores to Generate Highly Stable Luminescent Carbon-Centered Radicals
    T. SUMI, R. GOSEKI, H. OTSUKA
    Chem. Commun., 57, 11885-11888 (2017).
    DOI: 10.1039/C7CC06913H

  79. Photoregulation of Retro-Diels–Alder Reaction at the Center of Polymer Chains
    J. KIDA, K. IMATO, R. GOSEKI, M. MORIMOTO, H. OTSUKA
    Chem. Lett., 46, 992-994 (2017).
    DOI: 10.1246/cl.170251

  80. Dynamic covalent diarylbibenzofuranone-modified nanocellulose: Mechanochromic behaviour and application in self-healing polymer composites
    K. IMATO, J. C. NATTERODT, J. SAPKOTA, R. GOSEKI, C. WEDER, A. TAKAHARA, H. OTSUKA
    Polym. Chem., 8, 2115-2122 (2017).
    DOI: 10.1039/c7py00074j

  81. A vinylic rotaxane cross-linker for toughened network polymers from the radical polymerization of vinyl monomers
    J. SAWADA, D. AOKI, M. KUZUME, K. NAKAZONO, H. OTSUKA, T. TAKATA
    Polym. Chem., 8, 1878-1881 (2017).
    DOI: 10.1039/c7py00193b

  82. Synthesis of Rotaxane Cross-linked Polymers with Supramolecular Cross-linkers Based on γ-CD and PTHF Macromonomers: The Effect of the Macromonomer Structure on the Polymer Properties
    K. IIJIMA, D. AOKI, H. OTSUKA, T. TAKATA
    Polymer, 128, 392-396 (2017).
    DOI: 10.1016/j.polymer.2017.01.024

  83. Thermally Adjustable Dynamic Disulfide Linkages Mediated by Highly Air-Stable 2,2,6,6-Tetramethylpiperidine-1-sulfanyl (TEMPS) Radicals (Accepted Frontispiece)
    A. TAKAHASHI, R. GOSEKI, H. OTSUKA
    Angew. Chem. Int. Ed., 56, 2016-2021 (2017).
    DOI: 10.1002/anie.201611049

  84. Enhancing Mechanochemical Activation in the Bulk State by Designing Polymer Architectures
    H. OKA, K. IMATO, T. SATO, T. OHISHI, R. GOSEKI, H. OTSUKA
    ACS Macro Lett., 5, 1124-1127 (2016).
    DOI: 10.1021/acsmacrolett.6b00529

  85. Polymer-Inorganic Composites with Dynamic Covalent Mechanochromophore
    T. KOSUGE, K. IMATO, R. GOSEKI, H. OTSUKA
    Macromolecules, 49, 5903-5911 (2016).
    DOI: 10.1021/acs.macromol.6b01333

  86. Repeatable Mechanochemical Activation of Dynamic Covalent Bonds in Thermoplastic Elastomers
    K. IMATO, T. KANEHARA, S. NOJIMA, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Chem. Commun., 52, 10482-10485 (2016).
    DOI: 10.1039/c6cc04767j

  87. Facile Modification and Fixation of Diaryl Disulphide-containing Dynamic Covalent Polyesters by Iodine-catalysed Insertion-like Addition Reactions of Styrene Derivatives to Disulphide Units
    Y. NAKAI, A. TAKAHASHI, R. GOSEKI, H. OTSUKA
    Polym. Chem., 7, 4661-4666 (2016).
    DOI: 10.1039/c6py00963h

  88. Triggered Structural Control of Dynamic Covalent Aromatic Polyamides: Effects of Thermal Reorganization Behavior in Solution and Solid States
    M. AIBA, T. HIGASHIHARA, M. ASHIZAWA, H. OTSUKA, H. MATSUMOTO
    Macromolecules, 49, 2153-2161 (2016).
    DOI: 10.1021/acs.macromol.5b01778

  89. Degradable Epoxy Resins Prepared from Diepoxide Monomer with Dynamic Covalent Disulfide Linkage
    A. TAKAHASHI, T. OHISHI, R. GOSEKI, H. OTSUKA
    Polymer, 82, 319-326 (2016).
    DOI: 10.1016/j.polymer.2015.11.057

  90. Autonomously Substitutable Organosilane Thin Films Based on Dynamic Covalent Diarylbibenzofuranone Units
    R. YONEYAMA, T. SATO, K. IMATO, T. KOSUGE, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Chem. Lett., 45, 36-38 (2016).
    DOI: 10.1246/cl.150917

  91. Radical Crossover Reactions of Alkoxyamine-Based Dynamic Covalent Polymer Brushes on Nanoparticles and the Effect on Their Dispersibility
    T. SATO, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Polym. J., 48, 147-155 (2016).
    DOI: 10.1038/pj.2015.94

  92. Mechanochromic Dynamic Covalent Elastomers: Quantitative Stress Evaluation and Autonomous Recovery
    K. IMATO, T. KANEHARA, T. OHISHI, M. NISHIHARA, H. YAJIMA, M. ITO, A. TAKAHARA, H. OTSUKA
    ACS Macro Lett., 4, 1307-1311 (2015).
    DOI: 10.1021/acsmacrolett.5b00717

  93. Metathesis-driven Scrambling Reactions between Polybutadiene or Naturally Occurring Polyisoprene and Olefin-containing Polyurethane
    T. OHISHI, K. SUYAMA, S. KAMIMURA, M. SAKADA, K. IMATO, S. KAWAHARA, A. TAKAHARA, H. OTSUKA
    Polymer, 78, 145-153 (2015).
    DOI: 10.1016/j.polymer.2015.09.076

  94. Self-Healing of a Cross-Linked Polymer with Dynamic Covalent Linkages at Mild Temperature and Evaluation at Macroscopic and Molecular Levels
    K. IMATO, A. TAKAHARA, H. OTSUKA
    Macromolecules, 48, 5632-5639 (2015).
    DOI: 10.1021/acs.macromol.5b00809

  95. Diarylbibenzofuranone-Based Dynamic Covalent Polymer Gels Prepared via Radical Polymerization and Subsequent Polymer Reaction
    K. IMATO, N. NISHIHARA, A. IRIE, A. TAKAHARA, H. OTSUKA
    Gels, 1, 58-68 (2015).
    DOI: 10.3390/gels1010058

  96. Synthesis of Vinylic Macromolecular Rotaxane Cross-Linkers Endowing Network Polymers with Toughness
    J. SAWADA, D. AOKI, S. UCHIDA, H.OTSUKA, T. TAKATA
    ACS Macro Lett., 4, 598-601 (2015).
    DOI: 10.1021/acsmacrolett.5b00242

  97. Mechanophores with a Reversible Radical System and Freezing-Induced Mechanochemistry in Polymer Solutions and Gels
    K. IMATO, A. IRIE, T. KOSUGE, T. OHISHI, M. NISHIHARA, A. TAKAHARA, H. OTSUKA
    Angew. Chem. Int. Ed., 54, 6168-6172 (2015).
    DOI: 10.1002/anie.201412413

  98. Polyurethane Nanocomposites Reinforced with Surface Modified Halloysite Nanotubes
    H. JING, Y. HIGAKI, T. ISHIKAWA, K. L. WHITE, H. OTSUKA, A. TAKAHARA
    Sci. Adv. Mater., 7, 974-980 (2015)
    DOI: 10.1166/sam.2015.2040

  99. Synthesis of Polyethylene/polyester Copolymers through Main Chain Exchange Reactions via Olefin Metathesis
    T. MAEDA, S. KAMIMURA, T. OHISHI, A. TAKAHARA, H. OTSUKA
    Polymer, 55, 6245-6251 (2014)
    DOI: 10.1016/j.polymer.2014.10.001

  100. Network Reorganization of Dynamic Covalent Polymer Gels with Exchangeable Diarylbibenzofuranone at Ambient Temperature
    K. IMATO, T. OHISHI, M. NISHIHARA, A. TAKAHARA, H. OTSUKA
    J. Am. Chem. Soc., 136, 11839-11845 (2014)
    DOI: 10.1021/ja5065075

  101. Plasticizer-Promoted Thermal Cross-linking of a Dynamic Covalent Polymer with Complementarily Reactive Alkoxyamine Units in the Side Chain under Bulk Conditions
    J. SU, K. IMATO, T. SATO, T. OHISHI, A. TAKAHARA, H. OTSUKA
    Bull. Chem. Soc. Jpn., 87, 1023-1025 (2014)
    DOI: 10.1246/bcsj.20140147

  102. Radical Crossover Reactions of a Dynamic Covalent Polymer Brush for Reversible Hydrophilicity Control
    T. SATO, Y. AMAMOTO, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Polymer, 55, 4586-4592 (2014)
    DOI: 10.1016/j.polymer.2014.07.010

  103. Preparation and Characterization of Polycarbonate Nanocomposites Based on Surface-modified Halloysite Nanotube
    H. JING, Y. HIGAKI, W. MA, J. XI, H. JINNAI, H. OTSUKA, A. TAKAHARA
    Polym. J., 46, 307-312 (2014)
    DOI: 10.1038/pj.2013.100

  104. Reversible Cross-linking Reactions of Alkoxyamine-appended Polymers under Bulk Conditions for Transition between Flow and Rubber-like State
    J. SU, Y. AMAMOTO, T. SATO, M. KUME, T. INADA, T. OHISHI, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Polymer, 55, 1474-1480 (2014)
    DOI: 10.1016/j.polymer.2014.01.055

  105. Insertion Metathesis Depolymerization of Aromatic-Disulfide-Containing Dynamic Covalent Polymers under Weak Intensity Photoirradiation
    T. OHISHI, Y. IKI, K. IMATO, Y. HIGAKI, A. TAKAHARA, H. OTSUKA
    Chem. Lett., 42, 1346-1348 (2013)
    DOI: 10.1246/cl.130639

  106. Reversibly Crosslinked Polymeric Micelles Formed by Autonomously Exchangeable Dynamic Covalent Bonds
    M. NISHIHARA, K. IMATO, A. IRIE, T. KANEHARA, A. KANO, A. MARUYAMA, A. TAKAHARA, H. OTSUKA
    Chem. Lett., 42, 377-379 (2013)
    DOI: 10.1246/cl.121289

  107. Internally Modified Halloysite Nanotubes as Inorganic Nanocontainers for a Flame Retardant
    H. JING, Y HIGAKI, W. MA, H. WU, W. O. YAH, H. OTSUKA, Y. LVOV, A. TAKAHARA
    Chem. Lett., 42, 121-123 (2013)
    DOI: 10.1246/cl.2013.1211

  108. Preparation of novel polyimide hybrid materials by multi-layered charge-transfer complex formation
    R. WATARI, M. NISHIHARA, H. TAJIRI, H. OTSUKA, A. TAKAHARA
    Polym. J., 45, 839-844 (2013)
    DOI: 10.1038/pj.2012.222

  109. Structural Effects of Catechol-Containing Polystyrene Gels Based on Dual Cross-linking Approach
    H. XU, J. NISHIDA, H. WU, Y. HIGAKI, H. OTSUKA, N. OHTA, A. TAKAHARA
    Soft Matter, 9, 1967-1974 (2013)
    DOI: 10.1039/C2SM26994E

  110. Perfluoropolyether-infused Nano-texture: A Versatile Approach to Omniphobic Coatings with Low Hysteresis and High Transparency
    W. MA, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Chem. Commun., 49, 597-599 (2013)
    DOI: 10.1039/c2cc37576a

  111. Dynamic Covalent Polymer Brushes: Reversible Surface Modification of Reactive Polymer Brushes with Alkoxyamine-based Dynamic Covalent Bonds
    T. SATO, Y. AMAMOTO, H. YAMAGUCHI, T. OHISHI, A. TAKAHARA, H. OTSUKA
    Polym. Chem., 3, 3077-3083 (2012)
    DOI: 10.1039/C2PY20294H

  112. Self-Healing of Covalently Cross-Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under Visible Light
    Y. AMAMOTO, H. OTSUKA, A. TAKAHARA, and K. MATYJASZEWSKI
    Adv. Mater., 24, 3975-3980 (2012)
    DOI: 10.1002/adma.201201928

  113. A“non-sticky” superhydrophobic surface by self-assembly of fluoroalkyl phosphonic acid on a hierarchically micro/nanostructured alumina gel film
    W. MA, H. WU, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Chem. Commun., 48, 6824-6826 (2012)
    DOI: 10.1039/C2CC32513F

  114. Changes in Network Structure of Chemical Gels Controlled by Solvent Quality through Photoinduced Radical Reshuffling Reactions of Trithiocarbonate Units
    Y. AMAMOTO, H. OTSUKA, A. TAKAHARA, K. MATYJASZEWSKI
    ACS Macro Lett., 1, 478-481 (2012)
    DOI: 10.1021/mz300070t

  115. Competition between Oxidation and Coordination in Cross-linking of Polystyrene Copolymer Containing Catechol Groups
    H. XU, J. NISHIDA, W. MA, H. WU, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
    ACS Macro Lett., 1, 457-460 (2012)
    DOI: 10.1021/mz200217d

  116. Preparation and Characterization of Imogolite/DNA Hybrid Hydrogels
    N. JIRAVANICHANUN, K. YAMAMOTO, K. KATO, J. KIM, S. HORIUCHI, W. O. YAH, H. OTSUKA, A. TAKAHARA
    Biomacromolecules., 13, 276-281 (2012)
    DOI: 10.1021/bm201616m

  117. Self-healing of Chemical Gels Cross-linked by Diarylbibenzofuranone-based Trigger-free Dynamic Covalent Bonds at Room Temperature
    K. IMATO, M. NISHIHARA, T. KANEHARA, Y. AMAMOTO, A. TAKAHARA, H. OTSUKA
    Angew. Chem. Int. Ed., 51, 1138-1142 (2012)
    DOI: 10.1002/anie.201104069

  118. Preparation and Properties of PVC/PMMA-g-imogolite Nanohybrid via Surface-Initiated Radical Polymerization
    W. MA, H. OTSUKA, A. TAKAHARA
    Polymer, 52, 5543-5550 (2011)
    DOI: 10.1016/j.polymer.2011.09.054

  119. Reversible Cross-linking of Hydrophilic Dynamic Covalent Polymers with Radically Exchangeable Alkoxyamines in Aqueous Media
    S. JING, Y. AMAMOTO, M. NISHIHARA, A. TAKAHARA, H. OTSUKA
    Polym. Chem., 2, 2021-2026 (2011)
    DOI: 10.1039/C1PY00176K

  120. Molecular Aggregation State and Electrical Properties of Terthiophenes/Imogolite Nanohybrids
    W. O. YAH, A. IRIE, N. JIRAVANICHANUN, H. OTSUKA, A. TAKAHARA
    Bull. Chem. Soc. Jpn., 84, 893-902 (2011)
    DOI: 10.1246/bcsj.20110080

  121. Poly(methyl methacrylate) Grafted Imogolite Nanotubes Prepared through Surface-initiated ARGET ATRP
    W. MA, H. OTSUKA, A. TAKAHARA
    Chem. Commun., 47, 5813-5815 (2011)
    DOI: 10.1039/C1CC10661A

  122. Preparation of Superparamagnetic β-Cyclodextrin-functionalized Composite Nanoparticles with Core-shell Structures
    R.-X. LI, S.-M. LIU, J.-Q. ZHAO, H. OTSUKA, A. TAKAHARA
    Polym. Bull., 66, 1125-1136 (2011)
    DOI: 10.1007/s00289-010-0410-y

  123. Preparation and Characterization of Cross-linked Beta-cyclodextrin Polymer/Fe3O4 Composite Nanoparticles with Core-shell Structures
    R.-X. LI, S.-M. LIU, J.-Q. ZHAO, H. OTSUKA, A. TAKAHARA
    Chinese Chem. Lett., 22, 217-220 (2011)
    DOI: 10.1016/j.cclet.2010.09.014

  124. Surface Modification of Individual Imogolite Nanotubes with Alkyl Phosphate from an Aqueous Solution
    W. MA, J. KIM, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 40, 159-161 (2011)
    DOI: 10.1246/cl.2011.159

  125. Mesh-Size Control and Functionalization of Reorganizable Chemical Gels by Monomer Insertion into Their Cross-Linking Points
    Y. AMAMOTO, M. KIKUCHI, H. MASUNAGA, H. OGAWA, S. SASAKI, H. OTSUKA, A. TAKAHARA
    Polym. Chem., 2, 957-962 (2011)
    DOI: 10.1039/C0PY00304B

  126. Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of Trithiocarbonate Units
    Y. AMAMOTO, J. KAMADA, H. OTSUKA, A. TAKAHARA, K. MATYJASZEWSKI
    Angew. Chem. Int. Ed., 50, 1660-1663 (2011)
    DOI: 10.1002/anie.201003888

  127. “Substitutable” Polymer Brushes: Reactive Poly(methacrylate) Brushes with Exchangeable Alkoxyamine Units in the Side Chain
    T. SATO, Y. AMAMOTO, H. YAMAGUCHI, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 39, 1209-1211 (2010)
    DOI: 10.1246/cl.2010.1209

  128. Arm-replaceable Star-like Nanogels: Arm Detachment and Arm Exchange Reactions by Dynamic Covalent Exchanges of Alkoxyamine Units
    Y. AMAMOTO, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
    Polym. J., 42, 860-867 (2010)
    DOI: 10.1038/pj.2010.83

  129. Influence of Magadiite Dispersion States on the Flammability of Polystyrene and Polyphenylene Ether-Polystyrene Alloy Nanocomposites
    H. YUKUTAKE, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
    Polym. J., 42, 223-231 (2010)
    DOI: 10.1038/pj.2009.336

  130. Solvent-Controlled Formation of Star-like Nanogels via Dynamic Covalent Exchange of PSt-b-PMMA Diblock Copolymers with Alkoxyamine Units in the Side Chain
    Y. AMAMOTO, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 43, 5470-5473 (2010)
    DOI: 10.1021/ma100276n

  131. Intelligent Build-Up of Complementarily Reactive Diblock Copolymers via Dynamic Covalent Exchange toward Symmetrical and Miktoarm Star-like Nanogels
    Y. AMAMOTO, M. KIKUCHI, H. MATSUNAGA, S. SASAKI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 43, 1785-1791 (2010)
    DOI: 10.1021/ma902413f

  132. A Dynamic Covalent Polymer Driven by Disulfide Metathesis under Photoirradiation
    H. OTSUKA, S. NAGANO, Y. KOBASHI, T. MAEDA, A. TAKAHARA
    Chem. Commun., 46, 1150-1152 (2010)
    DOI: 10.1039/B916128G

  133. Reorganizable Chemical Polymer Gels Based on Dynamic Covalent Exchange and Controlled Monomer Insertion
    Y. AMAMOTO, M. KIKUCHI, H. MASUNAGA, S. SASAKI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 42, 8733-8738 (2009)
    DOI: 10.1021/ma901746n

  134. Molecular Aggregation State and Photovoltaic Properties of Chlorophyll-Doped Conducting Poly(3-hexylthiophene)/MCM-41 Nanocomposites
    W. O. YAH, Z. WANG, H. OTSUKA, K. KATO, J. KIM, M. TAKATA, A. TAKAHARA
    ACS Appl. Mater. Interfaces, 1, 1544-1552 (2009)
    DOI: 10.1021/am9002099

  135. Thermal Degradation Behavior of Polystyrene/magadiite Nanocomposites Prepared by Surface-initiate Nitroxide-mediated Radical Polymerization
    H. YUKUTAKE, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
    Polym. J., 41, 555-561 (2009)
    DOI: 10.1295/polymj.PJ2009044

  136. Scrambling Reaction between Polymers Prepared by Step-growth and Chain-growth Polymerizations: Macromolecular Cross-metathesis between 1,4-Polybutadiene and Olefin-containing Polyester
    H. OTSUKA, T. MUTA, M. SAKADA, T. MAEDA, A. TAKAHARA
    Chem. Commun., 45, 1073-1074 (2009)
    DOI: 10.1039/B818014H

  137. Rational Approach to Star-like Nanogels with Different Arm Lengths: Formation by Dynamic Covalent Exchange and Their Imaging
    Y. AMAMOTO, T. MAEDA, M. KIKUCHI, H. OTSUKA, A. TAKAHARA
    Chem. Commun., 45, 689-691 (2009)
    DOI: 10.1039/B818049K

  138. Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by Spin-Assembly
    N. JIRAVANICHANUN, K. YAMAMOTO, H. YONEMURA, S. YAMADA, H. OTSUKA, A.TAKAHARA
    Bull. Chem. Soc. Jpn., 81, 1663-1668 (2008)
    DOI: 10.1246/bcsj.81.1663

  139. Control of Dispersion State of Silsesquioxane Nanofillers for Stabilization of Polystyrene Thin Films
    N. HOSAKA, N. TORIKAI, M. HINO, H. OTSUKA, A. TAKAHARA
    Langmuir, 24, 5766-5772 (2008)
    DOI: 10.1021/la704062n

  140. Dewetting Inhibition and Interfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films
    K. MIYAMOTO, N. HOSAKA, M. KOBAYASHI, H. OTSUKA, N. YAMADA, N. TORIKAI, A. TAKAHARA
    Polym. J., 39, 1247-1252 (2007)
    DOI: 10.1295/polymj.PJ2007067

  141. Programmed Thermodynamic Formation and Structure Analysis of Star-like Nanogels with Core Cross-linked by Thermally Exchangeable Dynamic Covalent Bonds
    Y. AMAMOTO, Y. HIGAKI, Y. MATSUDA, H. OTSUKA, A. TAKAHARA
    J. Am. Chem. Soc.,129, 13298-13304 (2007)
    DOI: 10.1021/ja075447n

  142. Programmed Formation of Nanogels via a Radical Crossover Reaction of Complementarily Reactive Diblock Copolymers
    Y. AMAMOTO, Y. HIGAKI, Y. MATSUDA, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 36, 774-775 (2007)
    DOI: 10.1246/cl.2007.774

  143. Thermal Reorganization and Molecular Weight Control of Dynamic Covalent Polymers Containing Alkoxyamines in Their Main Chains
    H. OTSUKA, K. AOTANI, Y. HIGAKI, Y. AMAMOTO, A. TAKAHARA
    Macromolecules, 40, 1429-1434 (2007)
    DOI: 10.1021/ma061667u

  144. Structure and Dewetting Behavior of Polyhedral Oligomeric Silsesquioxane-Filled Polystyrene Thin Films
    N. HOSAKA, N. TORIKAI, H. OTSUKA, A. TAKAHARA
    Langmuir, 23, 902-907 (2007)
    DOI: 10.1021/la062255h

  145. Analysis of Molecular Aggregation States in Pentacene Thin Films Prepared from Soluble Precursor
    T. AKINAGA, S. YASUTAKE, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 35, 1162-1163 (2006)
    DOI: 10.1246/cl.2006.1162

  146. Stabilization of Polystyrene Thin Films against Dewetting by Silsesquioxane-terminated Polystyrene Additives
    K. MIYAMOTO, N. HOSAKA, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 35, 1098-1099 (2006)
    DOI: 10.1246/cl.2006.1098

  147. Facile Synthesis of Multiblock Copolymers Composed of Poly(tetramethylene oxide) and Polystyrene using Living Free-radical Polymerization Macroinitiator
    Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Polymer, 47, 3784-3791 (2006)
    DOI: 10.1016/j.polymer.2006.03.100

  148. Polystyrene-grafted Titanium Oxide Nanoparticles Prepared through Surface-initiated Nitroxide-mediated Radical Polymerization and Their Application to Polymer Hybrid Thin Films
    R. MATSUNO, H. OTSUKA, A. TAKAHARA
    Soft Matter, 2, 415-421 (2006)
    DOI: 10.1039/B601197G

  149. リジンイソシアナートを用いたセグメント化ポリウレタンウレアの特性解析と分解挙動
    波多野道子, 山口智弘, 大塚英幸、青井啓悟、佐々木園、高原淳
    日本ゴム協会誌, 79, 219-224 (2006)

  150. A Thermodynamic Polymer Cross-linking System Based on Radically Exchangeable Covalent Bonds
    Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 39, 2121-2125 (2006)
    DOI: 10.1021/ma052093g

  151. (Inorganic Nanofiber/Enzyme) Hybrid Hydrogel: Preparation, Characterization, and Enzyme Activity of Imogolite/Pepsin Conjugate
    N. INOUE, H. OTSUKA, S. WADA, A. TAKAHARA
    Chem. Lett., 35, 194-195 (2006)
    DOI: 10.1246/cl.2006.194

  152. Preparation and Properties of [Poly(methyl methacrylate)/Imogolite] Hybrid via Surface Modification using Phosphoric Acid Ester
    K. YAMAMOTO, H. OTSUKA, S. WADA, D. SOHN, A. TAKAHARA
    Polymer, 46, 12386-12392 (2005)
    DOI: 10.1016/j.polymer.2005.10.108

  153. Adsorbent for Di-n-butyl Phthalate using Chitosan Beads with Upper- or Lower-Rim Substituted Water-soluble Calixarenes
    A. YANAGI, H. OTSUKA, A. TAKAHARA
    Polym. J., 36, 939-945 (2005)
    DOI: 10.1295/polymj.37.939

  154. Tribological Properties of Poly(methyl methacrylate), Brushes Prepared by Surface-Initiated Atom Transfer Radical Polymerization
    H. SAKATA, M. KOBAYASHI, H. OTSUKA, A. TAKAHARA
    Polym. J., 36, 765-775 (2005)
    DOI: 10.1295/polymj.37.767

  155. Transparent Polymer Nanohybrid Prepared by in situ Synthesis of Aluminosilicate Nanofibers in Poly(vinyl alcohol) Solution
    K. YAMAMOTO, H. OTSUKA, S. WADA, D. SOHN, A. TAKAHARA
    Soft Matter, 1, 372-377 (2005)
    DOI: 10.1039/B508669H

  156. Imaging of Charged Micropatterned Monolayer Surfaces by Chemical Force Microscopy
    T. KOGA, H. OTSUKA, A. TAKAHARA
    Bull. Chem. Soc. Jpn., 78, 1691-1698 (2005)
    DOI: 10.1246/bcsj.78.1691

  157. Reversible Radical Ring-Crossover Polymerization of an Alkoxyamine-Conataining Dynamic Covalent Marcocycle
    G. YAMAGUCHI, Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 38, 6316-6320 (2005)
    DOI: 10.1021/ma0503209

  158. Rational Model for Chiral Recognition in a Silica-based Chiral Column: Chiral Recognition of N-(3,5-dinitrobenzoyl)phenylglycine- terminated Alkylsilane Monolayer by 2,2,2-Trifluoro-1-(9-anthryl)ethanol Derivatives by Chemical Force Microscopy
    H. OTSUKA, T. ARIMA, T. KOGA, A. TAKAHARA
    J. Phys. Org. Chem., 18, 957-961 (2005)
    DOI: 10.1002/poc.934

  159. Molecular Aggregation Structure of Poly(fluoroalkyl acrylate) Thin Films Evaluated by Synchrotron-Sourced Grazing-Incidence X-ray Diffraction
    K. HONDA, H. YAKABE, T. KOGA, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 34, 1024-1025 (2005)
    DOI: 10.1246/cl.2005.1024

  160. Molecular Aggregation Structure and Surface Properties of Poly(fluoroalkyl acrylate) Thin Films
    K. HONDA, M. MORITA, H. OTSUKA, A. TAKAHARA
    Macromolecules, 38, 5699-5705 (2005)
    DOI: 10.1021/ma050394k

  161. Macro- and Nanotribological Properties of Organosilane Monolayers Prepared by a Chemical Vapor Adsorption Method on Silicon Substrates
    H. ISHIDA, T. KOGA, M. MORITA, H. OTSUKA, A. TAKAHARA
    Tribology Lett., 19, 3-8 (2005)
    DOI: 10.1007/s11249-004-4259-9

  162. Adsorption of Di-n-butyl Phthalate by Chitosan Beads Modified with Water-soluble Calixarenes
    A. YANAGI, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 34, 218-219 (2005)
    DOI: 10.1246/cl.2005.218

  163. Macroscopic-Wetting Anisotropy on the Line-Patterned Surface of Fluoroalkylsilane Monolayers
    M. MORITA, T. KOGA, H. OTSUKA, A. TAKAHARA
    Langmuir, 21, 911-918 (2005)
    DOI: 10.1021/la0485172

  164. Dependence of the Molecular Aggregation State of Octadecylsiloxane Monolayers on Preparation Methods
    T. KOGA, M. MORITA, H. ISHIDA, H. YAKABE, S. SASAKI, O. SAKATA, H. OTSUKA, A. TAKAHARA
    Langmuir, 21, 905-910 (2005)
    DOI: 10.1021/la048544s

  165. Influence of the Addition of Silsesquioxane on the Dewetting Behavior of Polystyrene Thin Film
    N. HOSAKA, K. TANAKA, H. OTSUKA, A. TAKAHARA
    Composite Interfaces, 11, 297-306 (2004)
    DOI: 10.1163/1568554041738157

  166. Polystyrene- and Poly(3-vinylpyridine)-Grafted Magnetite Nanoparticles Prepared through Surface-Initiated Nitroxide-Mediated Radical Polymerization
    R. MATSUNO, K. YAMAMOTO, H. OTSUKA, A. TAKAHARA
    Macromolecules, 37, 2203-2209 (2004)
    DOI: 10.1021/ma035523g

  167. Dynamic Formation of Graft Copolymers via Radical Crossover Reaction of Alkoxyamines
    Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Macromolecules, 37, 1696-1701 (2004)
    DOI: 10.1021/ma035518c

  168. Synthesis of Well-Defined Poly(styrene)-b-poly(p-tert-butoxysturene) Multiblock Copolymer from Poly(alkoxyamine) Macroinitiator
    Y. HIGAKI, H. OTSUKA, A. TAKAHARA
    Polymer, 44, 7095-7101 (2003)
    DOI: 10.1016/j.polymer.2003.09.002

  169. Thin Silica Film with a Network Structure as Prepared by Surface Sol-Gel Transcription on the Poly(styrene-b-4-vinylpyridine) Polymer Film
    N. FUJITA, H. OTSUKA, A. TAKAHARA, S. SHINKAI
    Chem. Lett., 32, 352-353 (2003)
    DOI: 10.1246/cl.2003.352

  170. Polymer Scrambling: Macromolecular Radical Crossover Reaction between the Main Chains of Alkoxyamine-Based Dynamic Covalent Polymers
    H. OTSUKA, K. AOTANI, Y. HIGAKI, A. TAKAHARA
    J. Am. Chem. Soc., 125, 4064-4065 (2003)
    DOI: 10.1021/ja0340477

  171. Polystyrene-Grafted Magnetite Nanoparticles Prepared through Surface-Initiated Nitroxyl-Mediated Radical Polymerization
    R. MATSUNO, K. YAMAMOTO, H. OTSUKA, A. TAKAHARA
    Chem. Mater., 15, 3-5 (2003)
    DOI: 10.1021/cm020766t

  172. Polyurethane Macroinitiator for Controlled Monomer Insertion of Styrene
    Y. HIGAKI, H. OTSUKA, T. ENDO, A. TAKAHARA
    Macromolecules, 36, 1494-1499 (2003)
    DOI: 10.1021/ma021091i

  173. Surface Structure and Properties of Multi-Component Micropatterned Organosilane Monolayers Prepared by Stepwise Photodecomposition and Chemisorption Process
    T. KOGA, M. MORITA, H. SAKATA, H. OTSUKA, A. TAKAHARA
    Int. J. Nanoscience, 1, 419-423 (2002)
    DOI: 10.1142/S0219581X02000437

  174. A Dynamic (Reversible) Covalent Polymer: Radical Crossover Behaviour of TEMPO-containing Poly(alkoxyamine ester)s
    H. OTSUKA, K. AOTANI, Y. HIGAKI, A. TAKAHARA
    Chem. Commun., 38, 2838-2839 (2002)
    DOI: 10.1039/B209193C

  175. Fabriaction of Three-Component Micropatterned Organosilane Monolayer by a Stepwise Photolithography Process
    K. KOGA, H. OTSUKA, A. TAKAHARA
    Chem. Lett., 31, 1196-1197 (2002)
    DOI: 10.1246/cl.2002.1196

  176. Pinacol Rearrangement in the Polymer Backbone: Synthesis of Novel Reactive Polymers with Condensed Benzopinacol Units in the Main Chain and Their Complete Rearrangement to Poly(benzopinacolone)s
    H. OTSUKA, I. ONOZUKA, T. SHIOYA, T. ENDO
    Macromol. Chem. Phys., 203, 1824-1832 (2002)
    DOI: 10.1002/1521-3935(200208)203:12<1824::AID-MACP1824>3.0.CO;2-#

  177. Preparation of Novel (Polymer/Inorganic Nanofiber) Composite through Surface Modification of Natural Aluminosilicate Nanofiber
    K. YAMAMOTO, H. OTSUKA, A. TAKAHARA, S. WADA
    J. Adhesion, 78, 591-602 (2002)
    DOI: 10.1080/00218460213740

  178. Surface Modification of Aluminosilicate Nanofiber "Imogolite"
    K. YAMAMOTO, H. OTSUKA, S. WADA, A. TAKAHARA
    Chem. Lett., 30, 1162-1163 (2001)
    DOI: 10.1246/cl.2001.1162

  179. Novel Reactive Polymers Containing Hemiacetal Ester and Vinyl Moieties: Synthesis and Selective Polymerization of 1-Methoxyallyl Methacrylate Derived from Methacrylic Acid and Methoxyallene
    H. OTSUKA, K-i. MORI, T. ENDO
    Macromol. Rapid Commun., Vol. 22, pp1335-1339 (2001)
    DOI: 10.1002/1521-3927(20011101)22:16<1335::AID-MARC1335>3.0.CO;2-I

  180. Fine Tuning of Thermal Dissociation Temperature in Copolymers with Hemiacetal Ester Moieties in the Side Chain: Effect of Comonomer Component on Dissociation Temperature
    H. OTSUKA, H. FUJIWARA, T. ENDO
    React. Funct. Polym., 46, 293-298 (2001)
    DOI: 10.1016/S1381-5148(00)00071-7

  181. Pinacol Rearrangement in the Polymer Backbone: New Class of Reactive Polymers with Condensed Benzopinacol Units in the Main Chain
    H. OTSUKA, I. ONOZUKA, T. ENDO
    Tetrahedron Lett., 41, 1433-1433 (2000)
    DOI: 10.1016/S0040-4039(99)02309-6

  182. Synthesis and Controlled Polymerization of p-(1-Methylcyclohexyloxy)styrene and Quick-Response Deblocking Ability of the Obtained Polymer
    H. OTSUKA, T. SATO, T. ENDO
    Macromol. Rapid Commun., 21, 48-52 (2000)
    DOI: 10.1002/(SICI)1521-3927(20000101)21:1<48::AID-MARC48>3.0.CO;2-A

  183. Thermal Dissociation Behavior of the Polymers with Hemiacetal Esters Moieties in the Side Chain: The Effect of Structure on Dissociation Temperature
    H. OTSUKA, H. FUJIWARA, T. ENDO
    J. Polym. Sci., Part A: Polym. Chem., 37, 4478-4482 (1999)
    DOI: 10.1002/(SICI)1099-0518(19991215)37:24<4478::AID-POLA2>3.0.CO;2-R

  184. Poly(hemiacetal ester)s: New Class of Polymers with Thermal Dissociative Units in the Main Chain
    H. OTSUKA, T. ENDO
    Macromolecules, 33, 9059-9061 (1999)
    DOI: 10.1021/ma9909408

  185. Guest Inclusion Properties of Calix[6]arene-based Unimolecular Cage Compounds. On Their High Cs+ and Ag+ Selectivity and Very Slow Exchange Rates
    H. OTSUKA, Y. SUZUKI, A. IKEDA, K. ARAKI, S. SHINKAI
    Tetrahedron, 54, 423-446 (1998)
    DOI: 10.1016/S0040-4020(97)10261-7

  186. Thermodynamic Studies of Slow Metal Exchange Processes in Ionophoric Calix[n]arene with a Capsule-like Closed Cavity
    Y. SUZUKI, H. OTSUKA, A. IKEDA, S. SHINKAI
    Tetrahedron Lett., 38, 421-425 (1997)
    DOI: 10.1016/S0040-4039(96)02315-5

  187. Definitive Evidence for Inhibition of Calix[6]arene Ring Inversion Obtained from a 1,3-Xylenyl-Bridged Chiral Calix[6]arene
    H. OTSUKA, S. SHINKAI
    J. Am. Chem. Soc., 118, 4271-4275 (1996)
    DOI: 10.1021/ja953626b

  188. Reinvestigation of Calixarene-Based Artificial-Signaling Acetylcholine Receptors Useful in Neutral Aqueous(Water/Methanol) Solution
    K. N. KOH, K. ARAKI, A. IKEDA, H. OTSUKA, S. SHINKAI,
    J. Am. Chem. Soc., 118, 755-758 (1996)
    DOI: 10.1021/ja951488k

  189. Metal-Induced Conformational Changes in Calix[6]arenes Can Change the Exchange Interaction between N-O・ Radicals
    K. ARAKI, R. NAKAMURA, H. OTSUKA, S. SHINKAI
    J. Chem. Soc., Chem. Commun., 31, 2121-2122 (1995)
    DOI: 10.1039/C39950002121

  190. Syntheses of All Possible Calix[6]arene Derivatives with MeO- and ROCOCH2O- Substituents and Their Metal Binding Properties
    H. OTSUKA, K. ARAKI, S. SHINKAI
    Tetrahedron, 51, 8757-8770 (1995)
    DOI: 10.1016/0040-4020(95)00466-L

  191. Syntheses and NMR Spectroscopic Studies of Bridged and Capped Calix[6]arenes: High-Yield Syntheses of Unimolecular Caged Compounds from Calix[6]arene
    H. OTSUKA, K. ARAKI, H. MATSUMOTO, T. HARADA, S. SHINKAI
    J. Org. Chem., 60, 4862-4867 (1995)
    DOI: 10.1021/jo00120a033

  192. Immobilization of the Ring Inversion Motion in Calix[6]arene by a Cap with C3-Symmetry
    K. ARAKI, K. AKAO, H. OTSUKA, K. NAKASHIMA, F. INOKUCHI, S. SHINKAI
    Chem. Lett., 23, 1251-1254 (1994)
    DOI: 10.1246/cl.1994.1251

  193. Syntheses of All Possible O-Methylation Products Derivable from 5,11,17,23,29,35-Hexa-tert-butylcalix[6]arene-37,38,39,40,41,42-hexol
    H. OTSUKA, K. ARAKI, S. SHINKAI
    J. Org. Chem., 59, 1542-1547 (1994)
    DOI: 10.1021/jo00085a048

  194. Rotation vs. Immobilization Controversy in Calix[6]arenes. Is 5,11,17,23,29,35-Hexa-tert-butyl-37,39,41-trimethoxy-38,40,42-tris (tert-butoxycarbonylmethoxy) calix[6]arene Really Immobilized?
    H. OTSUKA, K. ARAKI, T. SAKAKI, K. NAKASHIMA, S. SHINKAI
    Tetrahedron Lett., 34, 7275-7278 (1993)
    DOI: 10.1016/S0040-4039(00)79307-5

  195. Synthesis and Ion Selectivity of Conformers Derived from Hexahomotrioxacalix[3]arene
    K. ARAKI, M. HASHIMOTO, H. OTSUKA, S. SHINKAI
    J. Org. Chem., 58, 5958-5963 (1993)
    DOI: 10.1021/jo00074a021

  196. Conformational Isomerism in and Binding Properties to Alkali Metals and an Ammonium Salt of O-Alkylated Homooxacalix[3]arenas
    K. ARAKI, K. INADA, H. OTSUKA, S. SHINKAI
    Tetrahedron, 49, 9465-9478 (1993)
    DOI: 10.1016/S0040-4020(01)80216-7

  197. Unequivocal Evidence for the Para-Substituent-through- the-Annulus Rotation in Calix[6]arene
    H. OTSUKA, K. ARAKI, S. SHINKAI
    Chem. Expr., 8, 479-482 (1993)

  198. Molecular Design of a Calix[6]arene-Based SuperUranophile with C3-Symmetry. High UO22+ Selectivity in Solvent Extraction
    K. ARAKI, N. HASHIMOTO, H. OTSUKA, T. NAGASAKI, S. SHINKAI
    Chem. Lett., 22, 829-832 (1993)
    DOI: 10.1246/cl.1993.829

著書 -BOOK-

  1. TBA
    Y. LU, T. YAMAMOTO, H. OTSUKA
    Encyclopedia of Polymers, Polymeric Materials, and Polymer Technology, in press..

  2. 基礎高分子科学演習編 第2版
    高分子学会 編
    大塚英幸（分担執筆）
    東京化学同人, (2023).

  3. 高分子材料の事典
    高分子学会 編
    大塚英幸（分担執筆）
    朝倉書店, (2022).

  4. Cyclic Polymers Synthesized by Spontaneous Selective Cyclization Approaches
    Y. TEZUKA, T. DEGUCHI Eds., Topological Polymer Chemistry
    D, AOKI, H. OTSUKA, T. TAKATA
    Springer, pp.319–334 (2022).

  5. 動的共有結合を導入した異種架橋高分子間の混合一体化技術
    異種材料の接着・接合技術と応用事例
    大塚英幸
    技術情報協会, pp.269-275 (2021).

  6. 動的共有結合化学に基づく自己修復材料の開発
    伊藤 耕三、高原 淳、原田 明 監修、ポリマーの強靱化技術最前線　～破壊機構、分子結合制御、しなやかタフポリマーの開発～
    大塚英幸
    エヌ・ティー・エス, (2020).

  7. 動的共有結合化学アプローチによる自己修復性高分子の開発
    自己修復材料、自己組織化、形状記憶材料の開発と応用事例
    大塚英幸
    技術情報協会, pp15-21 (2020).

  8. 基礎高分子科学 第2版
    高分子学会 編
    大塚英幸（分担執筆）
    東京化学同人, (2020)

  9. Mechanochromic Polymers as Stress-sensing Soft Materials
    H. KOSHIMA Ed., Mechanically Responsive Materials for Soft Robotics
    D, AOKI, H. OTSUKA
    Wiley-VCH, pp.307-323 (2019)

  10. 動的共有結合ポリマー
    日本化学会 編 CSJカレントレビュー　超分子ポリマー
    大塚英幸, 青木大輔
    化学同人, pp82-90 (2019).

  11. 自己修復性高分子材料に関する最近の研究開発動向
    ゴム技術フォーラム 編, ゴム・エラストマー技術の安全・安心
    大塚英幸
    ポスティコーポレーション, pp15-22 (2019)

  12. 動的共有結合化学に基づく自己修復性高分子材料の設計
    宮田隆志 監修, 刺激応答性高分子ハンドブック
    大塚英幸, 青木大輔
    エヌ・ティー・エス (2018)

  13. 最新潮流 高分子系自己修復材料
    日経BP総研, 日経 x TECH 編、スマートマテリアル総覧 自己修復材料編
    大塚英幸
    日経BP (2018)

  14. 最新材料一覧 動的共有結合
    日経BP総研, 日経 x TECH 編、スマートマテリアル総覧 自己修復材料編
    大塚英幸
    日経BP (2018)

  15. ラジカル的な炭素−炭素結合交換反応を用いる自己修復性ポリマー
    松本章一 監修、新材料・新素材シリーズ　リビングラジカル重合　−機能性高分子の合成と応用展開−
    大塚英幸
    シーエムシー出版, pp186-192 (2018)

  16. ニトロキシドを用いるリビングラジカル重合と動的共有結合ポリマー
    松本章一 監修、新材料・新素材シリーズ　リビングラジカル重合　−機能性高分子の合成と応用展開−
    大塚英幸
    シーエムシー出版, pp11-17 (2018)

  17. Responsive Dynamic-Covalent Polymers: Self-Healing Polymers through Dynamic Covalent Chemistry
    Wei ZHANG, Yinghua JIN Eds., Dynamic Covalent Chemistry: Principles, Reactions and Applications
    K. IMATO, H. OTSUKA
    Wiley, pp359–387 (2017)

  18. PET (Poly(ethylene terephthalate)) & PTT (Poly(trimethylene terephthalate))
    S. KOBAYASHI, K. MULLEN Eds., Encyclopedia of Polymeric Nanomaterials
    T. OHISHI, H. OTSUKA
    Springer, pp1534-1538 (2015)

  19. Dynamic Covalent PN (Polymer Nanomaterials)
    S. KOBAYASHI, K. MULLEN Eds, Encyclopedia of Polymeric Nanomaterials
    H. OTSUKA, T. OHISHI
    Springer, pp636-641 (2015)

  20. 動的共有結合を有する化学ゲル
    中野義夫 監修, ゲルテクノロジーハンドブック
    大塚英幸, 後関頼太
    エヌ・ティー・エス, pp202-208 (2014)

  21. 組み換え可能な共有結合を有する化学架橋システム
    有光晃二 監修, ラドテック研究会 編集, UV・EB硬化技術の最新応用展開
    大塚英幸, 後関頼太
    シーエムシー出版, pp131-138 (2014)

  22. 動的共有結合を利用した修復材料
    編集代表 西 敏夫, 高分子ナノテクノロジーハンドブック -最新ポリマーABC技術を中心として-
    大塚英幸
    エヌ・ティー・エス, pp440-445 (2014)

  23. 動的共有結合化学に基づく化学架橋高分子の合成と反応メカニズム
    架橋の反応・構造制御と分析 事例集
    大塚英幸
    技術情報協会, pp9-15 (2014)

  24. Self-healing Polymers
    McGraw-Hill Yearbook of Science and Technology 2014
    H. OTSUKA
    McGraw-Hill Education, pp337-340 (2014)

  25. 自己修復性化学ゲルの設計
    ゲルの安定化と機能性付与・次世代への応用開発
    大塚英幸
    技術情報協会, pp461-465 (2013)

  26. ラジカルプロセスに基づく架橋高分子の合成と反応（角岡正弘、白井正充 監修）　高分子の架橋と分解III
    大塚英幸
    シーエムシー出版, pp148-158 (2012)

  27. Synthesis and Characterization of Polymeric Nanogels
    C. S. S. R. Kumar Ed., Polymeric Nanomaterials
    Y. AMAMOTO, H. OTSUKA, A. TAKAHARA
    Wiley-VCH (2011)

  28. Structure and Properties of Imogolite Nanotubes and Their Application to Polymer Nanocomposites
    T. KIJIMA Ed., Inorganic and Metallic Nanotubular Materials
    H. OTSUKA, A. TAKAHARA
    Springer, pp229-260 (2010)

  29. Dynamic Combinatorial Methods in Materials Science
    B. L. MILLER Ed., Dynamic Combinatorial Chemistry in Drug Delivery, Bioorganic Chemistry and Materials Science
    T. MAEDA, H. OTSUKA, A. TAKAHARA
    Wiley, pp229-260 (2009)

  30. Synthesis and Reaction of Well-defined Copolymers with Thermally Exchangeable Dynamic Covalent Bonds in K. Matyjaszewski Ed., ACS Symposium Series Vol.1024 Controlled/Living
    Radical Polymerization: Progress in RAFT, DT,NMP & OMRP
    H. OTSUKA, Y. AMAMOTO, Y. MATSUDA, T. MAEDA, A. TAKAHARA
    American Chemical Society, pp319-329 (2009)

  31. 高機能化を指向したポリウレタンのナノレベル複合化
    ポリウレタン 最新開発動向
    大塚英幸、高原　淳
    情報機構, pp203-214 (2009)

  32. イモゴライトチューブ
    国武豊喜 監修, 超分子 サイエンス&テクノロジー
    大塚英幸、高原　淳
    エヌ・ティー・エス, pp841-848 (2009)

  33. 次世代共役ポリマーの超階層制御と革新機能 (赤木和夫 監修) 第II編
    赤木和夫 監修, 次世代共役ポリマーの超階層制御と革新機能
    大塚英幸
    シーエムシー出版社 (2009)

  34. 無機ナノ構造体を基盤とする共役ポリマーの超階層制御
    第２章　生分解性ポリウレタンの高次構造とその特性
    波多野道子、小林元康、大塚英幸、高原　淳
    技術情報協会 (2007)

  35. かご型シルセスキオキサン添加高分子薄膜の分子凝集状態と熱的性質
    伊藤真樹 監修, シルセスキオキサン材料の化学と応用展開
    穂坂　直、宮本郷太、大塚英幸、高原　淳
    シーエムシー出版社, pp265-277 (2007)

  36. ポリウレタンのハイブリッド化
    最新 ポリウレタンの設計・改質と高機能化　技術全集
    大塚英幸, 高原　淳
    技術情報協会, pp265-277 (2007)

  37. 動的共有結合化学による架橋システム
    松本章一 監修, 接着とはく離のための高分子
    大塚英幸
    シーエムシー出版社, 139-149 (2006)

  38. 精密高分子合成を用いた表面ナノ構造の精密制御
    新海征治 編著, モレキュラーインフォーマティクスを拓く分子機能材料
    高原　淳, 大塚英幸
    日刊工業新聞社 (2006)

  39. 反応性高分子の新展開（遠藤 剛 監修） 第８章 弱い共有結合を利用した高分子の合成と反応
    遠藤 剛 監修, 反応性高分子の新展開
    大塚英幸, 遠藤 剛
    シーエムシー出版社, 123-137 (2005)

総説・解説 -REVIEW-

  1. Mechanochromic Polymers Based on Radical-type Dynamic Covalent Chemistry
    T. YAMAMOTO, A. TAKAHASHI, H. OTSUKA
    Bull. Chem. Șoc. Jpn., 97, uoad004 (2024).
    DOI: 10.1093/bulcsj/uoad004

  2. Enhancing the Reactivity of Mechanically Responsive Units via Macromolecular Design
    T. WATABE, H. OTSUKA
    Macromolecules, 57, 425-433 (2024).
    DOI: 10.1021/acs.macromol.3c01280

  3. 力学応答性分子を有するマルチネットワークポリマーの強靭化と高感度メカノクロミズム
    大塚英幸
    ポリマーTECH, 19, No. 11 pp.38-41 (2023).

  4. ラジカル系の動的共有結合化学に基づく架橋高分子の自己修復
    大塚英幸, 高橋 明
    ファインケミカル, 52, No. 9 pp.32-38 (2023).

  5. 実感できる高分子の化学反応に魅せられて　-高分子反応にスポットライトを-
    大塚英幸
    化学と工業, 76, No. 7, 486-488 (2023).

  6. 力学応答性分子骨格の導入によるエラストマーの強靭化と力の可視化
    渡部拓馬, 大塚英幸
    日本ゴム協会誌, 96, No.5, pp.132- (2023).

  7. 化学の力で、未来社会で活躍する高分子をつくる
    大塚英幸
    螢雪時代, 4月臨時増刊, pp. 614 (2023).

  8. プラスチックを肥料に変換するリサイクルシステム
    青木大輔, 大塚英幸
    コンバーテック, 3月号 (2022).

  9. 高分子鎖を可視化する分子プローブ
    青木大輔, 大塚英幸
    化学と工業, 74, 664 (2021).

  10. 動的共有結合化学に基づく反応性および自己修復性高分子の設計
    大塚英幸
    接着の技術, 41, No.2, 16-20 (2021).

  11. 受けた力を色と蛍光で表現する高分子材料
    大塚英幸
    化学, Vol. 76, No. 6, 48-51 (2021).

  12. 組み換わる共有結合を利用した自己修復性高分子材料とその展開
    大塚英幸
    化学と教育, No. 3, 90-93 (2021).

  13. 動的共有結合化学を利用した自己修復性高分子および新規高付加価値ウレタン含有ジエン系ゴム材料の設計
    大塚英幸、青木大輔、庄田靖宏、角田克彦
    日本ゴム協会誌, No. 2, 33-38 (2021).

  14. p-位にマレイミド構造を持つフェニルイソシアネート誘導体を用いた高分子修飾とその応用
    青木大輔、高嶋力任、大塚英幸
    ネットワークポリマー, 42, No.1 30-37 (2021).
    DOI: 10.11364/networkedpolymer.42.1_30

  15. 動的共有結合化学に基づく架橋高分子の接着 : 自己修復性高分子の設計技術を架橋高分子の融合に展開
    大塚英幸
    月刊プラスチックス, 71, No.11, 43-37 (2020).

  16. 高分子反応を利用したメカノクロミックポリマー
    大塚英幸, 青木大輔
    高分子, 69, 515-517 (2020).

  17. 自己修復性高分子材料に関する研究開発動向
    大塚英幸
    自動車技術, 73, 18-23 (2019)

  18. 動的共有結合を有する反応性ポリウレタン
    大塚英幸，青木大輔
    日本接着学会誌, 55, 168-174 (2019)

  19. 自己修復性高分子材料の研究開発動向
    大塚英幸
    日本機械学会　機械材料・材料加工部門ニュースレター, 56, 4-5 (2018)

  20. Reorganizable and stimuli-responsive polymers based on dynamic carbon?carbon linkages in diarylbibenzofuranones Reactions by Dynamic Covalent Exchanges of Diarylbibenzofuranones
    K. IMATO, H. OTSUKA
    Polymer, 137, 395-413 (2018)
    DOI: 10.1016/j.polymer.2018.01.038

  21. 動的共有結合化学に基づくメカノクロミックエラストマーの設計
    大塚英幸
    日本ゴム協会誌, 90, 195-199 (2017)

  22. 自己修復性高分子
    大塚英幸
    高分子, 65, 624-625 (2016)

  23. 動的な炭素-炭素結合を利用した高分子新素材を目指して
    大塚英幸, 後関頼太
    繊維学会誌, 72, 332 (2016)

  24. 可逆的な炭素-炭素結合に基づく動的共有結合ポリマーゲル
    今任景一, 後関頼太, 大塚英幸
    ネットワークポリマー, 37, 31-40 (2016)

  25. 動的共有結合ポリマーの開発　-自在に構造変換できる高分子を目指して-
    大塚英幸, 後関頼太, 今任景一
    化学と教育, 64, 98-101 (2016)

  26. 自己修復性高分子の開発動向と構造変換可能な架橋高分子
    大塚英幸
    ペトロテック, 38, 774-778 (2015)

  27. 高分子鎖を介して分子を引っ張る！-力で生じる化学反応
    今任景一, 後関頼太, 大塚英幸
    化学, 70, 70-71 (2015)

  28. 動的共有結合化学に基づく高分子の自己修復
    今任景一, 大塚英幸
    日本画像学会誌, 54, 221-228 (2015)

  29. 完全自己修復性をもつ高分子ゲルの設計
    今任景一, 大塚英幸
    接着の技術, 35, 16-22, (2015)

  30. 動的共有結合化学に基づくアルコキシアミン骨格を有するラジカル反応性高分子の設計
    佐藤知哉, 赤嶺経太, 高原　淳, 大塚英幸
    高分子論文集, 72, 341-353 (2015)
    DOI: 10.1295/koron.2015-0006

  31. 進化する高分子設計 -共有結合系における高分子の構造・物性の自在変換-
    大塚英幸
    現代化学, No. 530, 24-28 (2015)

  32. 動的共有結合を利用した完全自己修復性ポリマーの開発
    今任景一、後関頼太、大塚英幸
    ファインケミカル, 43, 12, 13-20 (2014)

  33. 組み換え可能な共有結合を利用する反応性ソフトマテリアルの創製
    大塚英幸
    日本ゴム協会誌, 87, 29-32 (2014)

  34. 自己修復性ソフトマテリアルの最前線
    大塚英幸, 大石智之
    金属, 83, 1034-1038 (2013)

  35. 自発的な結合組み換え反応を利用する自己修復性化学ゲル
    大塚英幸, 今任景一, 大石智之, 高原　淳
    工業材料, 61, 879-891 (2013)

  36. 組み換え可能な共有結合を利用した架橋高分子の構造再編成と自己修復
    大塚英幸
    Rad Tech Japan News Letter, 88, 5-8, (2013)

  37. Reorganization of Polymer Structures Based on Dynamic Covalent Chemistry: Polymer Reactions by Dynamic Covalent Exchanges of Alkoxyamine Units
    H. OTSUKA
    Polym. J., 45, 879-891 (2013).
    DOI: 10.1038/pj.2013.17

  38. ラジカル反応を利用した反応性化学架橋高分子の設計
    大塚英幸, 高原淳
    ネットワークポリマー,. 33, 3, 154-159 (2012)

  39. Application of Imogolite Clay Nanotubes in Organic/Inorganic Nanohybrid Materials
    W. MA, W. O. YAH, H. OTSUKA, A. TAKAHARA
    J. Mater. Chem., 22, pp11887-11892 (2012)
    DOI: 10.1039/C2JM31570J

  40. 自発的に組み換わる動的共有結合を有する架橋高分子の合成と自己修復挙動
    今任景一, 大塚英幸
    日本接着学会誌, 48, 5,156-162 (2012)

  41. Surface Functionalization of Aluminosilicate Nanotubes with Organic Molecules
    W. MA, W. O. YAH, H. OTSUKA, A. TAKAHARA
    Beilstein Journal of Nanotechnology, 3, 82-100 (2012)
    DOI: 10.3762/bjnano.3.10

  42. 構造再編成可能な動的共有結合ポリマー
    天本義史, 大塚英幸
    高分子, 60, 324-328 (2011)

  43. 高分子主鎖のスクランブリング反応
    大塚英幸
    ファインケミカル, 39, 9, 5-13 (2010)

  44. Imogolite Reinforced Nanocomposites: Multifaceted Green Materials
    W. O. YAH, K. YAMAMOTO, N. JIRAVANICHANUN, H. OTSUKA, A. TAKAHARA
    Materials, Vol. 3, pp1709-1745 (2010)
    DOI: 10.3390/ma3031709

  45. 動的共有結合に基づく構造変換可能な高分子材料
    大塚英幸
    日本接着学会誌, 46, 122-128 (2010)

  46. 生分解性ポリウレタンとそのポリ乳酸ブレンドの構造
    白波瀬朋子, 波多野道子, 大塚英幸, 高原　淳
    日本ゴム協会誌, Vol. 82, pp349-355 (2009)

  47. 高機能化を指向した異種高分子の主鎖交換反応
    大塚英幸
    ファインケミカル, 38, 8, 43-52 (2009)

  48. Dynamic Covalent Polymers: Reorganizable Polymers with Dynamic Covalent Bonds
    T. MAEDA, H. OTSUKA, A. TAKAHARA
    Prog. Polym. Sci., 34, 581-604 (2009)
    DOI: 10.1016/j.progpolymsci.2009.03.001

  49. 動的共有結合化学を用いた精密高分子合成と高分子複合化 -自在に構造再編成 可能な高分子の創製を目指して-
    大塚英幸
    化学と工業, 62, 626-630 (2009)

  50. Preparation of Novel Polymer Hybrids from Imogolite Nanofiber
    K. YAMAMOTO, H. OTSUKA, A. TAKAHARA
    Polym. J., 39, 1-15 (2007)
    DOI: 10.1295/polymj.PJ2006128

  51. 「動的共有結合化学」に基づく分子構築・集積： 超分子、高分子の新しい合成 プロトコル
    高田十志和, 大塚英幸
    有機合成化学協会誌, 64, 194-207 (2006)

  52. 架橋高分子の共有結合を光で自在に組み換える
    大塚英幸
    化学, 61, 60 (2006)

  53. Precise surface structure control of inorganic solid and metal oxide nanoparticles through surface-initiated radical polymerization
    M.KOBAYASHI, R. MATSUNO, H. OTSUKA, A. TAKAHARA
    Sci. Tech. Adv. Mater.,7, 617-628 (2006)
    DOI: 10.1016/j.stam.2006.07.008

  54. ポリマーブラシによる固体表面の精密構造制御
    松野亮介, 小林元康, 大塚英幸, 高原　淳
    化学, 60, 70-71 (2005)

  55. 動的共有結合を有する反応性高分子の主鎖組み換え反応とナノ複合化への展開
    大塚英幸
    高分子加工, 54, 483-488 (2005)

  56. 動的共有結合を利用する高分子の構造再編成
    大塚英幸
    高分子, 53, 597 (2004)

  57. Fabrication and Characterization of Multi-component Organosilane Nanofilms
    A. TAKAHARA, H. SAKATA, M. MORITA, T. KOGA, H. OTSUKA
    Composite Interfaces, 10, 489-504 (2003)
    DOI: 10.1163/156855403771953713

  58. 天然ナノファイバー「イモゴライト」とそのナノハイブリッド化
    高原　淳、大塚英幸、山本和弥、和田信一郎
    工業材料, 51, 50-53 (2003)

  59. 「弱い共有結合」を基盤とする反応性高分子の設計 -ヘミアセタールエステルの 化学を利用した高分子設計-
    大塚英幸
    日本接着学会誌, 38, 27-32 (2002)

  60. 1-アルコキシカルボキシレートを基盤とする外部刺激応答性高分子の開発
    大塚英幸
    ネットワークポリマー, 20, 177 (1999)

  61. Stereochemical Control of Calixarenes Useful as Rigid Conformationally Diversiform Platforms for Molecular Design
    H. OTSUKA, S. SHINKAI
    Supramol. Sci., 3, 189-207 (1997)
    DOI: 10.1016/S0968-5677(96)00038-7

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〒152-8550
東京都目黒区大岡山2-12-1　
東京科学大学
物質理工学院　応用化学系

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